5H-二苯并[a,d]环庚烯合成路线 （共 55 条）
反应条件
iodine in neat (no solvent)
T=85°C;
参考文献
Jereb, Marjan; Vrazic, Dejan
Organic and Biomolecular Chemistry, 2013 , vol. 11, # 12 p. 1978 - 1999
反应条件
1: 92 percent / hydrogen / 5percent Pd-C / ethyl acetate
2: 77 percent / methyllithium / diethyl ether / 3 h / other tricyclic cyclopropylidene precursors, reaction regiospecificity
3: 65 percent / AgClO4 / benzene / 24 h / Ambient temperature
4: 20 mg / 2,3-dichloro-5,6-dicyanobenzoquinone / benzene / 24 h / Ambient temperature
View Scheme
参考文献
Paquette,L.A.; Chamot,E.; Brown,A.R.
Journal of the American Chemical Society, 1980 , vol. 102, p. 637
反应条件
1: 41 percent / potassium tert-butoxide / benzene; pentane / 10.5 h
2: 92 percent / hydrogen / 5percent Pd-C / ethyl acetate
3: 77 percent / methyllithium / diethyl ether / 3 h / other tricyclic cyclopropylidene precursors, reaction regiospecificity
4: 65 percent / AgClO4 / benzene / 24 h / Ambient temperature
5: 20 mg / 2,3-dichloro-5,6-dicyanobenzoquinone / benzene / 24 h / Ambient temperature
View Scheme
参考文献
Paquette,L.A.; Chamot,E.; Brown,A.R.
Journal of the American Chemical Society, 1980 , vol. 102, p. 637
反应条件
T=490°C; P=0.01 Torr;
参考文献
Wentrup, Curt; Mayor, Claude; Becker, Juergen; Lindner, Hans Joerg
Tetrahedron, 1985 , vol. 41, # 8 p. 1601 - 1612
反应条件
1: 65 percent / AgClO4 / benzene / 24 h / Ambient temperature
2: 20 mg / 2,3-dichloro-5,6-dicyanobenzoquinone / benzene / 24 h / Ambient temperature
View Scheme
参考文献
Paquette,L.A.; Chamot,E.; Brown,A.R.
Journal of the American Chemical Society, 1980 , vol. 102, p. 637
反应条件
1: 77 percent / methyllithium / diethyl ether / 3 h / other tricyclic cyclopropylidene precursors, reaction regiospecificity
2: 65 percent / AgClO4 / benzene / 24 h / Ambient temperature
3: 20 mg / 2,3-dichloro-5,6-dicyanobenzoquinone / benzene / 24 h / Ambient temperature
View Scheme
参考文献
Paquette,L.A.; Chamot,E.; Brown,A.R.
Journal of the American Chemical Society, 1980 , vol. 102, p. 637
反应条件
water in acetonitrile
0.25 h; Irradiation;
参考文献
Budac, David; Wan, Peter
Journal of Organic Chemistry, 1992 , vol. 57, # 3 p. 887 - 894
反应条件
iodine; hypophosphorous ether in acetic acid
Reduction; 24 h; Heating;
参考文献
Hicks; Han; Fry
Tetrahedron Letters, 2000 , vol. 41, # 41 p. 7817 - 7820
反应条件
H-ZSM-5 β mesoporous zeolite
T=300°C; Inert atmospherePyrolysis;
参考文献
Istrati, Daniela; Parvulescu, Luminitza; Popescu, Angela; Mihaiescu, Dan; Badea, Florin
Revue Roumaine de Chimie, 2010 , vol. 55, # 10 p. 711 - 714
反应条件
H-ZSM-5 β mesoporous zeolite
T=300°C; Inert atmospherePyrolysis;
参考文献
Istrati, Daniela; Parvulescu, Luminitza; Popescu, Angela; Mihaiescu, Dan; Badea, Florin
Revue Roumaine de Chimie, 2010 , vol. 55, # 10 p. 711 - 714
