2,2,6,6-四甲基哌啶氧化物合成路线 （共 284 条）
反应条件
potassium bromide; potassium iodide in dichloromethane; water
参考文献
The Nutrasweet Company
Patent: US5856584 A1, 1999 ;
反应条件
in cyclohexane T=99.3°C; Decomposition; substitution; Product distribution; Further Variations:reaction partner concentration;
参考文献
Tian, Feng; Dolbier Jr., William R.
Organic Letters, 2000 , vol. 2, # 6 p. 835 - 837
反应条件
anhydrous iron chloride; oxygen; sodium sulfate in toluene T=60°C;
参考文献
Drouet, Fleur; Zhu, Jieping; Masson, Geraldine
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 18 p. 3563 - 3569
反应条件
pyridine; iron(III) chloride
24 h; Ambient temperature; Mechanism;
参考文献
Barton, Derek H. R.; Le Gloahec, Valerie N.; Smith, Jason
Tetrahedron Letters, 1998 , vol. 39, # 41 p. 7483 - 7486
反应条件
in dichloromethane
24 h; HeatingIrradiation;
参考文献
Gill, G. Bryon; Pattenden, Gerald; Reynolds, Stephen J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1994 , # 4 p. 369 - 378
反应条件
1: hexane carboxylic acid With n-butyllithium; diisopropylamine in tetrahydrofuran; hexane
T=-78 - -35°C; 1 h; Inert atmosphere;
2: 2,2,6,6-tetramethyl-1-piperidinyloxy, free radical With Fe(η5-C5H5)2(PF6) in tetrahydrofuran; hexane
T=-78°C; 0.5 h; Inert atmosphere;
参考文献
Dinca, Emanuela; Hartmann, Philip; Smrcek, Jakub; Dix, Ina; Jones, Peter G.; Jahn, Ullrich
European Journal of Organic Chemistry, 2012 , # 24 p. 4461 - 4482
反应条件
1: hexane carboxylic acid With n-butyllithium; diethylamine; lithium chloride in tetrahydrofuran; hexane
T=-78 - 0°C; 1.16667 h; Inert atmosphere;
2: 2,2,6,6-tetramethyl-1-piperidinyloxy, free radical With Fe(η5-C5H5)2(PF6) in tetrahydrofuran; hexane
T=-78°C; 0.5 h; Inert atmosphere;
参考文献
Dinca, Emanuela; Hartmann, Philip; Smrcek, Jakub; Dix, Ina; Jones, Peter G.; Jahn, Ullrich
European Journal of Organic Chemistry, 2012 , # 24 p. 4461 - 4482
反应条件
[Ir(dF(CF3)ppy)2(bpy)](PF6) in acetone
T=20°C; 12 h; Inert atmosphereUV-irradiation;
参考文献
Yasu, Yusuke; Koike, Takashi; Akita, Munetaka
Advanced Synthesis and Catalysis, 2012 , vol. 354, # 18 p. 3414 - 3420
反应条件
decacarbonyldimanganese (2) in dichloromethane
T=20°C; Addition; UV-irradiation;
参考文献
Gilbert, Bruce C.; Kalz, Wilhelm; Lindsay, Chris I.; McGrail, P. Terry; Parsons, Andrew F.; Whittaker, David T. E.
Journal of the Chemical Society, Perkin Transactions 1, 2000 , # 8 p. 1187 - 1194
反应条件
in benzene
Kinetics; protection from light, in an NMR tube, thermolysis at 69.0+/-0.2°C for about 28 h; addn. of heptane;
参考文献
Daikh, Brian E.; Finke, Richard G.
Journal of the American Chemical Society, 1991 , vol. 113, # 11 p. 4160 - 4172
