3-苄基-2-羟基环戊烯-2-酮合成路线 （共 6 条）
反应条件
hydrogenchloride; acetic acid
3 h; Heating;
参考文献
Jogi, Artur; Ilves, Marit; Paju, Anne; Pehk, Tonis; Kailas, Tiiu; Mueuerisepp, Aleksander-Mati; Lopp, Margus
Tetrahedron Asymmetry, 2008 , vol. 19, # 5 p. 628 - 634
反应条件
1: BF3*Et2O / CH2Cl2 / -78 - 20 °C
2: Amberlyst 15; TFA / 10 h / Heating
View Scheme
参考文献
Gao, Fuye; Burnell, D. Jean
Journal of Organic Chemistry, 2006 , vol. 71, # 1 p. 356 - 359
反应条件
1: dimethylformamide / 22 °C
2: aq. H3PO4 / dimethylformamide / 72 h / Heating
View Scheme
参考文献
Strunz, George M.; Lal, G. Sankar
Canadian Journal of Chemistry, 1982 , vol. 60, p. 572 - 573
反应条件
1: dimethylformamide / 22 °C
2: aq. H3PO4 / dimethylformamide / 72 h / Heating
View Scheme
参考文献
Strunz, George M.; Lal, G. Sankar
Canadian Journal of Chemistry, 1982 , vol. 60, p. 572 - 573
反应条件
1: lithium aluminium tetrahydride / diethyl ether / -10 °C
2: pyridine; dichloromethane / 20 h / 20 °C
3: copper(l) iodide / tetrahydrofuran / 2.33 h / 0 °C / |Inert atmosphere
4: water; osmium(VIII) oxide; 4-methylmorpholine N-oxide / tert-butyl alcohol / 72 h / 60 °C
5: water; lithium hydroxide hydrate; 1 platinum on carbon / acetonitrile / 5 h / 60 °C
View Scheme
参考文献
Reile, Indrek; Kalle, Sigrid; Werner, Franz; Jaerving, Ivar; Kudrjashova, Marina; Paju, Anne; Lopp, Margus
Tetrahedron, 2014 , vol. 70, # 22 p. 3608 - 3613
反应条件
1: pyridine; dichloromethane / 20 h / 20 °C
2: copper(l) iodide / tetrahydrofuran / 2.33 h / 0 °C / |Inert atmosphere
3: water; osmium(VIII) oxide; 4-methylmorpholine N-oxide / tert-butyl alcohol / 72 h / 60 °C
4: water; lithium hydroxide hydrate; 1 platinum on carbon / acetonitrile / 5 h / 60 °C
View Scheme
参考文献
Reile, Indrek; Kalle, Sigrid; Werner, Franz; Jaerving, Ivar; Kudrjashova, Marina; Paju, Anne; Lopp, Margus
Tetrahedron, 2014 , vol. 70, # 22 p. 3608 - 3613
