1-溴-4-(叔丁基磺酰基)苯合成路线 （共 17 条）
反应条件
bromine; acetic acid
T=20°C;
参考文献
Blaszczyk, Alfred; Elbing, Mark; Mayor, Marcel
Organic and Biomolecular Chemistry, 2004 , vol. 2, # 19 p. 2722 - 2724
反应条件
1: 4-(tert-butylsulfanyl)bromobenzene With magnesium in tetrahydrofuran
6 h; Heating;
2: 2-Iodothiophene With [1,3-bis(diphenylphosphino) propane] dichloronickel(II) in tetrahydrofuran
12 h; Heating;
参考文献
Touaibia, Mohamed; Desjardins, Marc-Andre; Provencal, Alexandre; Audet, Daniel; Medard, Christelle; Morin, Mario; Breau, Livain
Synthesis, 2004 , # 14 p. 2283 - 2288
反应条件
tetrakis(triphenylphosphine) palladium(0) in toluene
Stille cross-coupling; Heating;
参考文献
Pinault, Thomas; Cherioux, Frederic; Therrien, Bruno; Suess-Fink, Georg
Heteroatom Chemistry, 2004 , vol. 15, # 2 p. 121 - 126
反应条件
1: 89 percent / diisopropylamine / trans-bis(triphenylphosphane)platinum(II) chloride; CuI / tetrahydrofuran / 3 h / 70 °C
2: 98 percent / tetrabutylammonium fluoride trihydrate / tetrahydrofuran / 2 h / 20 °C
3: 70 percent / trans-bis(triphenylphosphane)platinum(II) chloride; CuI / diethylamine / 6 h / Heating
View Scheme
参考文献
Blaszczyk, Alfred; Elbing, Mark; Mayor, Marcel
Organic and Biomolecular Chemistry, 2004 , vol. 2, # 19 p. 2722 - 2724
反应条件
1.1: n-BuLi / tetrahydrofuran
1.2: 83 percent / tetrahydrofuran
2.1: 92 percent / NaBH4 / ethanol / 1 h / 20 °C
View Scheme
参考文献
Stuhr-Hansen, Nicolai; Christensen, Jorn B.; Harrit, Niels; Bjornholm, Thomas
Journal of Organic Chemistry, 2003 , vol. 68, # 4 p. 1275 - 1282
反应条件
(i) Mg, Et2O, (ii) /BRN= 1342734/; Multistep reaction;
参考文献
Marcuzzi,F.; Melloni,G.
Synthesis, 1976 , p. 451 - 452
反应条件
1: (i) Mg, Et2O, (ii) /BRN= 1342734/
2: Cl2 / CH2Cl2
View Scheme
参考文献
Marcuzzi,F.; Melloni,G.
Synthesis, 1976 , p. 451 - 452
