2,4,6-三(三氟甲基)苯甲酸合成路线 （共 4 条）
反应条件
2,2,6,6-tetramethylpiperidinyl-lithium in diethyl ether T=-25°C; 2 h;
参考文献
Schlosser, Manfred; Mongin; Porwisiak, Jacek; Dmowski, Wojciech; Bueker, Heinz H.; Nibbering, Nico M. M.
Chemistry - A European Journal, 1998 , vol. 4, # 7 p. 1281 - 1286
反应条件
1: 33 percent / SF4 / 6 h / 150 °C 2: 46 percent / 1.6 M n-BuLi / diethyl ether; hexane View Scheme
参考文献
Carr, G. E.; Chambers, R. D.; Holmes, T. F.; Parker, P. G.
Journal of Organometallic Chemistry, 1987 , vol. 325, p. 13 - 24
反应条件
phosphorus pentachloride in tetrachloromethane 1 h; Heating;
参考文献
Ahlemann, Jens-T; Roesky, Herbert W.; Noltemeyer, Mathias; Schmidt, Hans-G.; Markovsky, Leonid N.; Shermolovich, Yuri G.
Journal of Fluorine Chemistry, 1998 , vol. 87, # 1 p. 87 - 90
反应条件
1: 85 percent / PCl5 / CCl4 / 1 h / Heating 2: 90 percent / NH3 / acetone / 12 h / Heating 3: 75 percent / Br2, aq. KOH / 12 h / 0 °C View Scheme
参考文献
Ahlemann, Jens-T; Roesky, Herbert W.; Noltemeyer, Mathias; Schmidt, Hans-G.; Markovsky, Leonid N.; Shermolovich, Yuri G.
Journal of Fluorine Chemistry, 1998 , vol. 87, # 1 p. 87 - 90
