(1-氟乙烯基)甲基二苯基硅烷合成路线 （共 7 条）
反应条件
1: diphenyl(methyl)silyl chloride With lithium; iodine in tetrahydrofuran T=20°C; Metallation; 16 h; 2: vinylidene difluoride in tetrahydrofuran T=-78°C; Substitution; 0.5 h;
参考文献
Hanamoto, Takeshi; Harada, Shigeo; Shindo, Keiko; Kondo, Michio
Chemical Communications, 1999 , # 23 p. 2397 - 2398
反应条件
1: diphenyl(methyl)silyl chloride With iodine; lithium in tetrahydrofuran T=20°C; microwave irradiation; 2: vinylidene difluoride in tetrahydrofuran T=-78°C; 2.5 h;
参考文献
US2005/148649 A1, ;
Page/Page column 30 ;
反应条件
cesium fluoride in N,N-dimethyl-formamide T=80°C; 12 h;
参考文献
Journal of Fluorine Chemistry, , vol. 118, # 1-2 p. 99 - 101
反应条件
copper(l) iodide; cesium fluoride; tetrakis(triphenylphosphine) palladium(0) in various solvent(s) T=20°C;
参考文献
Hanamoto, Takeshi; Kobayashi, Tomoko
Journal of Organic Chemistry, 2003 , vol. 68, # 16 p. 6354 - 6359
反应条件
potassium fluoride; copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) in N,N-dimethyl-formamide T=25°C; 64 h; Product distribution; Further Variations:CatalystsReagentsSolventsTemperaturestime;
参考文献
Synlett, , # 2 p. 281 - 283
反应条件
copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); cesium fluoride in N,N-dimethyl-formamide T=20°C; 21 h; Title compound not separated from byproducts;
参考文献
Hanamoto, Takeshi; Kobayashi, Tomoko
Journal of Organic Chemistry, 2003 , vol. 68, # 16 p. 6354 - 6359
反应条件
copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); cesium fluoride in various solvent(s) T=42 - 45°C; 10 h; Title compound not separated from byproducts;
参考文献
Journal of Organic Chemistry, , vol. 68, # 16 p. 6354 - 6359
