反应条件
n-butyllithium; N,N,N',N,-tetramethylethylenediamine in diethyl ether; hexane Ar; ferrocene (53.8 mmol) suspnd. in hexane, hexane soln. of BuLi (107.5mmol) added, TMEDA (55.7 mmol) added dropwise, stirred at room temp. fo r 14 h, Et2O soln. of ligand (104.1 mmol) added dropwise, stirred for 30min; extd. (H2O), reextd. (CH2Cl2), org. layer washed (aq. HCl), dried (MgSO4), filtered, concd., chromd. (SiO2, CH2Cl2/hexane=1/1), dried;
参考文献
Barry, Kevin P.; Nataro, Chip
Inorganica Chimica Acta, 2009 , vol. 362, # 6 p. 2068 - 2070
