(2Z)-2-辛烯-1-醇合成路线 （共 45 条）
反应条件
toluene-4-sulfonic acid in methanol
T=20°C; Large scale reaction;
参考文献
Egger, Michael; Pellett, Patrina; Nickl, Kathrin; Geiger, Sarah; Graetz, Stephanie; Seifert, Roland; Heilmann, Joerg; Koenig, Burkhard
Chemistry - A European Journal, 2008 , vol. 14, # 35 p. 10978 - 10984
反应条件
1: With N,O-bis-(trimethylsilyl)-acetamide; [O3ReOSiPh3] in diethyl ether
T=0°C; 0.5 h;
2: With potassium carbonate in methanol
T=20°C; Title compound not separated from byproducts;
参考文献
Morrill, Christie; Grubbs, Robert H.
Journal of the American Chemical Society, 2005 , vol. 127, # 9 p. 2842 - 2843
反应条件
1: 2.) BF3*2AcOH / 1.) NH3(liquid), 2 h, 2.) from 40 to 45 deg C, 20 h
2: 78 percent / conc. HCl / methanol / 4 h
3: H2 / NIP-2
View Scheme
参考文献
Gocan, Alexandra; Gansca, Lucia; Oprean, Ioan
Revue Roumaine de Chimie, 1995 , vol. 40, # 3 p. 253 - 258
反应条件
1: TsOH / methanol / Heating
2: H2 / Lindlar catalyst / hexane
View Scheme
参考文献
Kuwahara; Sakuma
Agricultural and Biological Chemistry, 1982 , vol. 46, # 7 p. 1855 - 1860
反应条件
Pd-BaSO4 in methanol
P=760 Torr; Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Binns, Malcolm R.; Haynes, Richard K.; Lambert, Dale E.; Schober, Paul A.; Turner, Susan G.
Australian Journal of Chemistry, 1987 , vol. 40, # 2 p. 281 - 290
反应条件
ammonia; lithium
2 h;
参考文献
Yadav, J. S.; Reddy, P. Satyanarayana
Synthetic Communications, 1986 , vol. 16, # 9 p. 1119 - 1132
反应条件
O,O'-(R)-(1,1'-dinaphthyl-2,2'-diyl)-N,N'-di-(R,R)-1-phenylethylphosphoramidite; copper(II) bis(trifluoromethanesulfonate) in toluene
T=-78 - 0°C; 5 h; Title compound not separated from byproducts;
参考文献
Pineschi, Mauro; Del Moro, Federica; Crotti, Paolo; Di Bussolo, Valeria; Macchia, Franco
Journal of Organic Chemistry, 2004 , vol. 69, # 6 p. 2099 - 2105
反应条件
1: 1.) BuLi, HMPA / 1.) THF, -5 deg C, 10 min, 2.) THF, overnight
2: 88 percent / p-toluenesulfonic acid / methanol
3: 10percent Pd/BaSO4 / methanol / 760 Torr / Ambient temperature
View Scheme
参考文献
Binns, Malcolm R.; Haynes, Richard K.; Lambert, Dale E.; Schober, Paul A.; Turner, Susan G.
Australian Journal of Chemistry, 1987 , vol. 40, # 2 p. 281 - 290
反应条件
n-butyllithium; diisobutylaluminium hydride in tetrahydrofuran
T=-78°C; Yield given. Yields of byproduct given;
参考文献
Takacs, James M.; Helle, Mark A.; Seely, Franklin L.
Tetrahedron Letters, 1986 , vol. 27, # 11 p. 1257 - 1260
反应条件
1: 78 percent / conc. HCl / methanol / 4 h
2: H2 / NIP-2
View Scheme
参考文献
Gocan, Alexandra; Gansca, Lucia; Oprean, Ioan
Revue Roumaine de Chimie, 1995 , vol. 40, # 3 p. 253 - 258
