(2Z)-2-辛烯-1-醇合成路线 （共 45 条）
反应条件
1: 85 percent / PBr3, pyridine / diethyl ether / 12 h / Ambient temperature
2: 1.) LiNH2, liquid NH3 / 1.) THF, 2 h, 2.) 20 min
3: 90 percent / Na, liquid NH3 / tetrahydrofuran / 1 h
View Scheme
参考文献
Yadav, J. S.; Reddy, P. Satyanarayana
Synthetic Communications, 1986 , vol. 16, # 9 p. 1119 - 1132
反应条件
1: 1.) PBr3, 2.) EtMgBr, 3.) Ni(OAc)2, NaBH4, (CH2NH2)2 / 1.) Et2O, 2.) THF, 3.) EtOH
2: 1.) PBr3, 2.) EtMgBr, 3.) Ni(OAc)2, NaBH4, (CH2NH2)2 / 1.) Et2O, 2.) THF, 3.) EtOH
View Scheme
参考文献
Yadav; Bhanu; Dutta, Dinah
Tetrahedron, 1998 , vol. 54, # 15 p. 3929 - 3934
反应条件
1: 70.09 percent / NaI; BF3*Et2O / acetonitrile / 0 °C
2: 68.09 percent / Zn; CuI / ethanol; H2O / 0.67 h / 0 °C / sonication
3: 68 percent / KOH / ethanol / 2.5 h / Heating
View Scheme
参考文献
Singh; Kaur; Nayyar; Bhandari; Kad
Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2001 , vol. 40, # 5 p. 386 - 390
反应条件
1: 70.09 percent / NaI; BF3*Et2O / acetonitrile / 0 °C
2: 68.09 percent / Zn; CuI / ethanol; H2O / 0.67 h / 0 °C / sonication
View Scheme
参考文献
Singh; Kaur; Nayyar; Bhandari; Kad
Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2001 , vol. 40, # 5 p. 386 - 390
反应条件
1: PBr3 / diethyl ether
2: (i) Mg, (ii) Cu, THF
View Scheme
参考文献
Osbond,J.M.
Journal of the Chemical Society, 1961 , p. 5270 - 5275
