五氟化(4-硝基苯基)硫合成路线 （共 27 条）
反应条件
fluorine in acetonitrile T=20°C;
参考文献
British Nuclear Fuels plc
Patent: US6747178 B1, 2004 ;
Location in patent: Page column 6 ;
反应条件
potassium fluoride; bis(fluoroxy)methane T=-20 - -15°C;
参考文献
AIR PRODUCTS AND CHEMICALS, INC.
Patent: EP1484318 A1, 2004 ;
Location in patent: Page 10; 11 ;
反应条件
1: With bis(fluoroxy)methane in acetonitrile T=-20 - -15°C; 2: With cesium fluoride in acetonitrile
参考文献
Umemoto, Teruo; Garrick, Lloyd M.; Saito, Norimichi
Beilstein Journal of Organic Chemistry, 2012 , vol. 8, p. 461 - 471
反应条件
fluorine in acetonitrile T=-35 - -25°C;
参考文献
AIR PRODUCTS AND CHEMICALS, INC.
Patent: EP1484318 A1, 2004 ;
Location in patent: Page 12 ;
参考文献
British Nuclear Fuels plc
Patent: US5741935 A1, 1998 ;
反应条件
1: 99 percent / H2 / Raney nickel / ethanol 2: t-BuONO; CuBr2 / acetonitrile 3: 1-methyl-pyrrolidin-2-one / 5 h / 180 °C View Scheme
参考文献
Chimia, , vol. 58, # 3 p. 138 - 142
反应条件
1.1: H2 / 5 percent Pd/C / tetrahydrofuran 2.1: HBr; NaNO2 2.2: 46 percent / CuBr / 20 - 80 °C 3.1: t-BuLi / diethyl ether / -78 °C 3.2: 76 percent / diethyl ether / -40 - 20 °C View Scheme
参考文献
Kirsch, Peer; Bremer, Matthias; Heckmeier, Michael; Tarumi, Kazuaki
Angewandte Chemie - International Edition, 1999 , vol. 38, # 13-14 p. 1989 - 1992
反应条件
1.1: 48 percent / H2 / Pd/C / ethanol 2.1: NaNO2; conc. HCl / H2O / 0.17 h / 0 °C 2.2: 50 percent / KI / H2O / 0.5 h View Scheme
参考文献
Bowden, Roy D.; Comina, Paul J.; Greenhall, Martin P.; Kariuki, Benson M.; Loveday, Amanda; Philp, Douglas
Tetrahedron, 2000 , vol. 56, # 21 p. 3399 - 3408
反应条件
1: 99 percent / H2 / Raney nickel / ethanol 2: t-BuONO; CuBr2 / acetonitrile View Scheme
参考文献
Wang, Chao; Yu, Yan-Bo; Fan, Shilu; Zhang, Xingang
Organic Letters, 2013 , vol. 15, # 19 p. 5004 - 5007
反应条件
1.1: H2 / 5 percent Pd/C / tetrahydrofuran 2.1: HBr; NaNO2 2.2: 46 percent / CuBr / 20 - 80 °C 3.1: t-BuLi / diethyl ether / -70 °C 3.2: B(OMe)3 / diethyl ether / -70 - -20 °C 3.3: 58 percent / H2O2; H2SO4 / acetic acid; diethyl ether / 1 h / -20 - 35 °C View Scheme
参考文献
USTAV ORGANICKE CHEMIE A BIOCHEMIE AKADEMIE VED CESKE REPUBLIKY, v.v.i.; BEIER, Petr
Patent: WO2012/45290 A1, 2012 ;
