bis(η3-allyl-μ-chloropalladium(II)); N,N,N',N'-tetra(diphenylphosphinomethyl)benzene-1,3-diamine; potassium carbonate in N,N-dimethyl acetamide T=130°C; Suzuki-Miyaura Coupling; 20 h; Inert atmosphereSchlenk technique; TimeConcentration;

caesium carbonate; trimethylphosphane; tris(dibenzylideneacetone)dipalladium (0) in tetrahydrofuran; ethylene glycol dimethyl ether Suzuki reaction; 16 h; Heating;

(i) NaNO2, aq. H2SO4, (ii) /BRN= 969212/, NaOAc; Multistep reaction;

triphenylphosphine in 1,2-dichloro-benzene 6 h; Heating;