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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
4-甲基萘-2-醇
合成路线
（共 11 条）
1341041-04-0
→
反应条件
26207-06-7
4-甲基萘-2-醇
反应条件
tetrakis(triphenylphosphine) palladium(0); sodium hydrogencarbonate in 1-methyl-pyrrolidin-2-one T=120°C; Heck reaction; 2 h; Inert atmosphere;
参考文献
Dai, Yao; Feng, Xiujuan; Liu, Hesong; Jiang, Hua; Bao, Ming
Journal of Organic Chemistry, 2011 , vol. 76, # 24 p. 10068 - 10077
201230-82-2
+
24850-33-7
烯丙基三丁基锡
+
3433-80-5
2-溴溴苄
→
反应条件
反应条件
tetrakis(triphenylphosphine) palladium(0); sodium hydrogencarbonate in 1-methyl-pyrrolidin-2-one T=120°C; Stille coupling; P=2250.23 Torr; 4 h; AutoclaveInert atmosphere;
参考文献
Dai, Yao; Feng, Xiujuan; Liu, Hesong; Jiang, Hua; Bao, Ming
Journal of Organic Chemistry, 2011 , vol. 76, # 24 p. 10068 - 10077
3433-80-5
2-溴溴苄
→
反应条件
26207-06-7
4-甲基萘-2-醇
反应条件
1: tetrakis(triphenylphosphine) palladium(0) / acetonitrile / 2 h / 80 °C / 2250.23 Torr / Autoclave; Inert atmosphere 2: short basic alumina column / ethyl acetate 3: tetrakis(triphenylphosphine) palladium(0); sodium hydrogencarbonate / 1-methyl-pyrrolidin-2-one / 3 h / 120 °C / Inert atmosphere View Scheme
参考文献
Dai, Yao; Feng, Xiujuan; Liu, Hesong; Jiang, Hua; Bao, Ming
Journal of Organic Chemistry, 2011 , vol. 76, # 24 p. 10068 - 10077
4900-66-7
→
反应条件
26207-06-7
4-甲基萘-2-醇
反应条件
1: benzene; diethyl ether 2: hydrobromic acid View Scheme
参考文献
Repinskaya, I. B.; Shakirov, M. M.; Koltunov, K. Yu.; Koptyug, V. A.
Journal of Organic Chemistry USSR (English Translation), 1992 , vol. 28, # 5.2 p. 778 - 784
Zhurnal Organicheskoi Khimii, 1992 , vol. 28, # 5 p. 1005 - 1012
123-54-6
乙酰丙酮
→
反应条件
26207-06-7
4-甲基萘-2-醇
反应条件
1.1: toluene-4-sulfonic acid / methanol / 5 h / 55 °C 2.1: sodium t-butanolate / tetrahydrofuran / 2 h / 30 - 45 °C 2.2: 6 h / 55 °C 3.1: tetra-(n-butyl)ammonium iodide; boron trichloride / dichloromethane / 1.08 h / -78 - 0 °C / Inert atmosphere View Scheme
参考文献
BIOGEN IDEC MA INC.; THOMAS, Jermaine; LIU, Xiaogao; LIN, Edward, Yin-Shiang; ZHENG, Guo, Zhu; MA, Bin; CALDWELL, Richard, D.; GUCKIAN, Kevin, M.; KUMARAVEL, Gnanasambandam; TAVERAS, Arthur, G.
Patent: WO2011/17561 A1, 2011 ;
WO 2011/017561 A1
2845-83-2
4-甲氧基-3-戊烯-2-酮
→
反应条件
26207-06-7
4-甲基萘-2-醇
反应条件
1.1: sodium t-butanolate / tetrahydrofuran / 2 h / 30 - 45 °C 1.2: 6 h / 55 °C 2.1: tetra-(n-butyl)ammonium iodide; boron trichloride / dichloromethane / 1.08 h / -78 - 0 °C / Inert atmosphere View Scheme
参考文献
BIOGEN IDEC MA INC.; THOMAS, Jermaine; LIU, Xiaogao; LIN, Edward, Yin-Shiang; ZHENG, Guo, Zhu; MA, Bin; CALDWELL, Richard, D.; GUCKIAN, Kevin, M.; KUMARAVEL, Gnanasambandam; TAVERAS, Arthur, G.
Patent: WO2011/17561 A1, 2011 ;
WO 2011/017561 A1
1341041-04-0
→
反应条件
26207-06-7
4-甲基萘-2-醇
反应条件
1: short basic alumina column / ethyl acetate 2: tetrakis(triphenylphosphine) palladium(0); triethylamine / 1-methyl-pyrrolidin-2-one / 3 h / 120 °C / Inert atmosphere View Scheme
参考文献
Dai, Yao; Feng, Xiujuan; Liu, Hesong; Jiang, Hua; Bao, Ming
Journal of Organic Chemistry, 2011 , vol. 76, # 24 p. 10068 - 10077
3433-80-5
2-溴溴苄
→
反应条件
26207-06-7
4-甲基萘-2-醇
反应条件
1: tetrakis(triphenylphosphine) palladium(0) / acetonitrile / 2 h / 80 °C / 2250.23 Torr / Autoclave; Inert atmosphere 2: short basic alumina column / ethyl acetate 3: tetrakis(triphenylphosphine) palladium(0); triethylamine / 1-methyl-pyrrolidin-2-one / 3 h / 120 °C / Inert atmosphere View Scheme
参考文献
Dai, Yao; Feng, Xiujuan; Liu, Hesong; Jiang, Hua; Bao, Ming
Journal of Organic Chemistry, 2011 , vol. 76, # 24 p. 10068 - 10077
99984-68-6
→
反应条件
26207-06-7
4-甲基萘-2-醇
反应条件
2: iron; acetic acid 3: Diazotization View Scheme
参考文献
Vesely et al.
Collection of Czechoslovak Chemical Communications, 1929 , vol. 1, p. 493,514
100724-24-1
→
反应条件
26207-06-7
4-甲基萘-2-醇
反应条件
1: hydrogen chloride; ethanol 3: iron; acetic acid 4: Diazotization View Scheme
参考文献
Vesely et al.
Collection of Czechoslovak Chemical Communications, 1929 , vol. 1, p. 493,514
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