1: 41 percent / 1.) trifluoroacetic acid / methanol; CH2Cl2 / 1.) 2-3 deg C 70 min, 2.) 18 deg C 2 min, 20 min
2: 100 percent / H2 / 10percent palladized charcoal / acetic acid / 4 h / Ambient temperature
3: sodium amalgam, aq. acetic acid / 18 h / 37 °C / enzymes from Euglena gracilis
4: 1.) 2M aq. potassium hydroxide; 2.) sodium amalgam / 1.) tetrahydrofuran 20 deg C; 2.) 3-4 min
View Scheme
参考文献
Robinson, John A.; McDonald, Edward; Battersby, Alan R.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1985 , p. 1699 - 1710
1: 40 percent / trifluoroacetic acid / 2-3 deg C 70 min, CH2Cl2-CH3OH 18 deg C 2 min
2: 95 percent / H2 / 10percent palladized charcoal / acetic acid / 4 h / Ambient temperature
3: sodium amalgam, aq. acetic acid / 18 h / 37 °C / enzymes from Euglena gracilis
4: 1.) 2M aq. potassium hydroxide; 2.) sodium amalgam / 1.) tetrahydrofuran 20 deg C; 2.) 3-4 min
View Scheme
参考文献
Robinson, John A.; McDonald, Edward; Battersby, Alan R.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1985 , p. 1699 - 1710
1: H2 / 10percent palladized charcoal / tetrahydrofuran / 760 Torr / Ambient temperature
2: 40 percent / trifluoroacetic acid / 2-3 deg C 70 min, CH2Cl2-CH3OH 18 deg C 2 min
3: 95 percent / H2 / 10percent palladized charcoal / acetic acid / 4 h / Ambient temperature
4: sodium amalgam, aq. acetic acid / 18 h / 37 °C / enzymes from Euglena gracilis
5: 1.) 2M aq. potassium hydroxide; 2.) sodium amalgam / 1.) tetrahydrofuran 20 deg C; 2.) 3-4 min
View Scheme
参考文献
Robinson, John A.; McDonald, Edward; Battersby, Alan R.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1985 , p. 1699 - 1710
1: 100 percent / H2 / 10percent palladized charcoal / acetic acid / 4 h / Ambient temperature
2: sodium amalgam, aq. acetic acid / 18 h / 37 °C / enzymes from Euglena gracilis
3: 1.) 2M aq. potassium hydroxide; 2.) sodium amalgam / 1.) tetrahydrofuran 20 deg C; 2.) 3-4 min
View Scheme
参考文献
Robinson, John A.; McDonald, Edward; Battersby, Alan R.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1985 , p. 1699 - 1710
1: 95 percent / H2 / 10percent palladized charcoal / acetic acid / 4 h / Ambient temperature
2: sodium amalgam, aq. acetic acid / 18 h / 37 °C / enzymes from Euglena gracilis
3: 1.) 2M aq. potassium hydroxide; 2.) sodium amalgam / 1.) tetrahydrofuran 20 deg C; 2.) 3-4 min
View Scheme
参考文献
Robinson, John A.; McDonald, Edward; Battersby, Alan R.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1985 , p. 1699 - 1710
Robinson, John A.; McDonald, Edward; Battersby, Alan R.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1985 , p. 1699 - 1710
Robinson, John A.; McDonald, Edward; Battersby, Alan R.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1985 , p. 1699 - 1710
Robinson, John A.; McDonald, Edward; Battersby, Alan R.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1985 , p. 1699 - 1710
