[(N,N-二甲基氨基)甲基]三丁基锡烷合成路线 （共 14 条）
参考文献
Gmelin Handbook: Sn: Org.Verb.2, 1.1.2.5.2, page 276 - 305
反应条件
in diethyl ether byproducts: propane, MgCl2; dry atmosphere; addn. of one equiv. of ethereal soln. of C3H7MgCl to Bu3SnH (0.125 mol); exothermic reaction; white soln. refluxed (2 h); addn. of immonium salt (0.1 mol); stirring for 2 h at room temp.; hydrolysis at 0 ° C;; extn. with ether, evapn., distn.,;
参考文献
Elissondo, Bernard; Verlhac, Jean-Baptiste; Quintard, Jean-Paul; Pereyre, Michel
Journal of Organometallic Chemistry, 1988 , vol. 339, p. 267 - 276
反应条件
in diethyl ether byproducts: propane, MgClI; dry atmosphere; addn. of one equiv. of ethereal soln. of C3H7MgCl to Bu3SnH (0.125 mol); exothermic reaction; white soln. refluxed (2 h); addn. of immonium salt (0.1 mol); stirring for 2 h at room temp.; hydrolysis at 0 ° C;; extn. with ether, evapn., distn.,;
参考文献
Elissondo, Bernard; Verlhac, Jean-Baptiste; Quintard, Jean-Paul; Pereyre, Michel
Journal of Organometallic Chemistry, 1988 , vol. 339, p. 267 - 276
反应条件
n-butyllithium in diethyl ether; pentane under Ar, n-BuLi in pentane added dropwise to Me2NCH2SnCl3 in ether, heated for 10 h under reflux; ppt. sepd., solvent evapd. in vac., residue fractionally distd.; elem. anal.;
参考文献
Tzschach, A.; Uhlig, W.; Kellner, K.
Journal of Organometallic Chemistry, 1984 , vol. 266, # 1 p. 17 - 24
反应条件
in tetrahydrofuran 60°C, 2 h;;
参考文献
Gmelin Handbook: Sn: Org.Verb.2, 1.1.2.5.2, page 276 - 305
反应条件
(i) nBuLi, benzene, hexane, (ii) /BRN= 1209232/; Multistep reaction;
参考文献
Peterson,D.J.
Journal of the American Chemical Society, 1971 , vol. 93, p. 4027 - 4031
反应条件
n-butyllithium; tetrabutylstannane in hexane T=0°C;
参考文献
Becke, Frank; Heinemann, Frank W.; Rueffer, Tobias; Wiegeleben, Peter; Boese, Roland; Blaeser, Dieter; Steinborn, Dirk
Journal of Organometallic Chemistry, 1997 , vol. 548, # 2 p. 205 - 210
参考文献
Peterson,D.J.
Journal of the American Chemical Society, 1971 , vol. 93, p. 4027 - 4031
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Peterson
Journal of Organometallic Chemistry, 1970 , vol. 21, p. P63
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Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.5.1, page 94 - 98
反应条件
n-butyllithium in further solvent(s) byproducts: (CH3)2NCH2Li; in tetramethylethylenediamine;;
参考文献
Gmelin Handbook: Sn: Org.Verb.2, 1.1.2.5.2, page 276 - 305
反应条件
in hexane byproducts: (CH3)2NCH2Li; Ar-atmosphere; addn. of 1 equiv. of BuLi to soln. of amine (O°C,stirring);
参考文献
Steiborn, Dirk; Becke, Frank; Boese, Roland
Inorganic Chemistry, 1995 , vol. 34, p. 2625 - 2628
