[(N,N-二甲基氨基)甲基]三丁基锡烷合成路线 （共 14 条）
反应条件
in tetrahydrofuran; hexane byproducts: Me2NCH2MgMe, LiCH2NMe2; under anaerobic conditions; n-BuLi (0.07-0.1 equiv.) in n-hexane added at -78°C to Sn compd. (1 equiv.) in n-hexane, stirred at room temp. for 15 min; MgMe2 (1 equiv.) in THF added at -78°C; stirred for30 min; warmed to room temp.; 1 d; not isolated; identified by (119)Sn NMR spectra; >95percent conversion;
参考文献
Yousef, Rushdi I; Rueffer, Tobias; Schmidt, Harry; Steinborn, Dirk
Journal of Organometallic Chemistry, 2002 , vol. 655, # 1-2 p. 111 - 114
反应条件
(i) nBuLi, hexane, (ii) /BRN= 745854/, Et2O, (iii) H2O; Multistep reaction;
参考文献
Peterson,D.J.
Journal of the American Chemical Society, 1971 , vol. 93, p. 4027 - 4031
反应条件
in tetrahydrofuran; hexane
byproducts: Me2NCH2MgMe, LiCH2NMe2; under anaerobic conditions; n-BuLi (0.07-0.1 equiv.) in n-hexane added at -78°C to Sn compd. (1 equiv.) in n-hexane, stirred at room temp. for 15 min; MgMe2 (1 equiv.) in THF added at -78°C; stirred for30 min; warmed to room temp.; 1 d; not isolated; identified by (119)Sn NMR spectra; >95percent conversion;
参考文献
Yousef, Rushdi I; Rueffer, Tobias; Schmidt, Harry; Steinborn, Dirk
Journal of Organometallic Chemistry, 2002 , vol. 655, # 1-2 p. 111 - 114
反应条件
Yield given. Multistep reaction;
参考文献
Quintard, Jean-Paul; Elissondo, Bernard; Jousseaume, Bernard
Synthesis, 1984 , # 6 p. 495 - 498
