2,4,6-三甲基苯溴化镁合成路线 （共 186 条）
反应条件
1: tetrahydrofuran
2: toluene
3: O2 / toluene
View Scheme
参考文献
Eisch, John J.; Shafii, Babak; Odom, Jerome D.; Rheingold, Arnold L.
Journal of the American Chemical Society, 1990 , vol. 112, # 5 p. 1847 - 1853
参考文献
Collet,A.; Jacques,J.
Synthesis, 1972 , p. 38 - 39
反应条件
cerium(III) chloride; lithium chloride in tetrahydrofuran
T=0°C;
参考文献
Krasovskiy, Arkady; Kopp, Felix; Knochel, Paul
Angewandte Chemie - International Edition, 2006 , vol. 45, # 3 p. 497 - 500
参考文献
Zeon Corporation
Patent: EP1405840 A1, 2004 ;
Location in patent: Page 19 ;
参考文献
Lapkin,I.I.; Mukhina,R.G.
J. Gen. Chem. USSR (Engl. Transl.), 1961 , vol. 31, # 12 p. 4001 - 4006,3732 - 3736
参考文献
Carre
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1910 , vol. 151, p. 150
Bulletin de la Societe Chimique de France, 1910 , vol. <4> 7, p. 842
反应条件
1: diethyl ether; tetrahydrofuran
2: tetrahydrofuran
View Scheme
参考文献
Jutzi,P.; Langer,P.
Journal of Organometallic Chemistry, 1977 , vol. 132, p. 45 - 51
参考文献
Jutzi,P.; Langer,P.
Journal of Organometallic Chemistry, 1977 , vol. 132, p. 45 - 51
反应条件
1: not given
View Scheme
参考文献
Gmelin Handbook: B: B-Verb.9, 6.1, page 258 - 268
反应条件
1: 2,4,6-trimethylphenylmagnesium bromide With Pd-PEPPSI-IPent; zinc(II) chloride in tetrahydrofuran
T=23°C; 0.333333 h; Inert atmosphere;
2: 1-bromo-2,6-dimethyl-benzene in tetrahydrofuran
T=70°C; 2.5 h; Inert atmosphere;
参考文献
Calimsiz, Selcuk; Sayah, Mahmoud; Mallik, Debasis; Organ, Michael G.
Angewandte Chemie - International Edition, 2010 , vol. 49, # 11 p. 2014 - 2017
