双(2-甲氧基苯基)氯化膦合成路线 （共 5 条）
反应条件
hydrogenchloride in diethyl ether 10 h; Heating;
参考文献
SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.
Patent: WO2008/77908 A1, 2008 ;
Location in patent: Page/Page column 51-52 ;
反应条件
1: With magnesium; iodine in tetrahydrofuran 2: With phosphorus trichoride in tetrahydrofuran
参考文献
INEOS EUROPE LIMITED
Patent: EP1208108 B1, 2007 ;
Location in patent: Page/Page column 10 ;
反应条件
1: With tert.-butyl lithium in cyclohexane; pentane T=0 - 20°C; 15 h; 2: in diethyl ether T=20°C; 1 h; Further stages.;
参考文献
Luo, Shuji; Vela, Javier; Liet, Graham R.; Jordan, Richard F.
Journal of the American Chemical Society, 2007 , vol. 129, # 29 p. 8946 - 8947
反应条件
1: 2-methoxybromobenzene With magnesium in diethyl ether Inert atmosphereReflux; 2: N,N-diethylphosphoramidous dichloride in diethyl ether Inert atmosphere;
参考文献
Bowen, Lucy E.; Charernsuk, Manutsavin; Hey, Thomas W.; McMullin, Claire L.; Orpen, A. Guy; Wass, Duncan F.
Dalton Transactions, 2010 , vol. 39, # 2 p. 560 - 567
反应条件
1: 1.) BuLi, TMEDA, / 1.) hexane, RT; 19 h, 2.) hexane, RT; 20 h 2: HCL / diethyl ether / 10 h / Heating View Scheme
参考文献
McEwen, W. E.; Beaver, B. D.
Phosphorus and Sulfur and the Related Elements, 1985 , vol. 24, p. 259 - 273
