(E,Z)-2,6-二甲基-2,6-辛二烯-1,8-二醇合成路线 （共 7 条）
反应条件
in water 72 h; biosynthesis with N. cataria; (3H-labelled form); Yield given;
参考文献
Bellesia, Franco; Grandi, Romano; Pagnoni, Ugo M.; Pinetti, Adriano; Trave, Roberto
Phytochemistry (Elsevier), 1984 , vol. 23, # 1 p. 83 - 88
反应条件
<b>With</b> <a href="#" onclick="return RXDsubstances(event, this, '4267587', constants.ctx, '0')">potassium carbonate</a> <b>in</b> <a href="#" onclick="return RXDsubstances(event, this, '1098229', constants.ctx, '0')">methanol</a> <br />T=20°C; 4 h; <br /> <br />
参考文献
Bogazkaya, Anna M.; Von Buehler, Clemens J.; Kriening, Sebastian; Busch, Alexandrine; Seifert, Alexander; Pleiss, Juergen; Laschat, Sabine; Urlacher, Vlada B. Beilstein Journal of Organic Chemistry, 2014 , vol. 10, p. 1347 - 1353
反应条件
<b>Multi-step reaction with 4 steps<br /> </b>1: diethyl ether / 1.5 h / -20 °C<br />2: Jones reagent / acetone / 0.5 h / 0 °C<br />3: NaH / tetrahydrofuran / room temp., 1 h then 65 deg C 3 h<br />4: AlH<sub>3</sub> / diethyl ether / 1.5 h / -15 - 0 °C<br /> <br />
参考文献
Uesato; Kobayashi; Inouye Chemical and Pharmaceutical Bulletin, 1982 , vol. 30, # 3 p. 927 - 940
反应条件
<b>Multi-step reaction with 2 steps<br /> </b>1: NaH / tetrahydrofuran / room temp., 1 h then 65 deg C 3 h<br />2: AlH<sub>3</sub> / diethyl ether / 1.5 h / -15 - 0 °C<br /> <br />
参考文献
Uesato; Kobayashi; Inouye Chemical and Pharmaceutical Bulletin, 1982 , vol. 30, # 3 p. 927 - 940
反应条件
<b>Multi-step reaction with 3 steps<br /> </b>1: Jones reagent / acetone / 0.5 h / 0 °C<br />2: NaH / tetrahydrofuran / room temp., 1 h then 65 deg C 3 h<br />3: AlH<sub>3</sub> / diethyl ether / 1.5 h / -15 - 0 °C<br /> <br />
参考文献
Uesato; Kobayashi; Inouye Chemical and Pharmaceutical Bulletin, 1982 , vol. 30, # 3 p. 927 - 940
反应条件
<b>Multi-step reaction with 2 steps<br /> </b>1: SeO<sub>2</sub> <br />2: LiAlH<sub>4</sub> <br /> <br />
参考文献
Knapp, Holger; Straubinger, Markus; Fornari, Selenia; Oka, Noriaki; Watanabe, Naoharu; Winterhalter, Peter Journal of Agricultural and Food Chemistry, 1998 , vol. 46, # 5 p. 1966 - 1970
反应条件
<b>Multi-step reaction with 2 steps<br /> </b>1: SeO<sub>2</sub>, t-BuOOH / toluene / 120 h / Ambient temperature<br />2: LiAlH<sub>4</sub> / diethyl ether / 1 h<br /> <br />
参考文献
Dawson, Glenn W.; Pickett, John A.; Smiley, Diane W. M. Bioorganic and Medicinal Chemistry, 1996 , vol. 4, # 3 p. 351 - 361
