乙基(2Z)-2,3-二溴丙烯酸酯合成路线 （共 6 条）
反应条件
bromine in tetrachloromethane T=70°C; 0.5 h;
参考文献
Myers, Andrew G.; Alauddin, Mian M.; Fuhry, Mary Ann M.; Dragovich, Peter S.; Finney, Nathaniel S.; Harrington, Philip M.
Tetrahedron Letters, 1989 , vol. 30, # 50 p. 6997 - 7000
反应条件
bromine in tetrachloromethane T=-78°C; other solvents and temperatures; Product distribution;
参考文献
Myers, Andrew G.; Alauddin, Mian M.; Fuhry, Mary Ann M.; Dragovich, Peter S.; Finney, Nathaniel S.; Harrington, Philip M.
Tetrahedron Letters, 1989 , vol. 30, # 50 p. 6997 - 7000
反应条件
(i) Jones reagent, acetone, (ii) /BRN= 1718733/, H2SO4, (iii) Br2, CCl4; Multistep reaction. Title compound not separated from byproducts;
参考文献
McConnell,O.; Fenical,W.
Phytochemistry (Elsevier), 1977 , vol. 16, p. 367 - 374
反应条件
1: 58 percent / Pd(PPh3)4 / tetrahydrofuran / 72 h / 20 °C 2: 37percent HCl / aq. ethanol / 2.5 h / Heating 3: Bu3N / Pd(PPh3)4 / acetonitrile / 48 h / 65 °C / 760 Torr View Scheme
参考文献
Rossi, Renzo; Bellina, Fabio; Carpita, Adriano; Gori, Raffaele
Gazzetta Chimica Italiana, 1995 , vol. 125, # 9 p. 381 - 392
反应条件
1: (i) KOtBu, tBuOH, (ii) /BRN= 1904574/ 2: ethanol / Heating 3: H2 / PtO2 / ethanol 4: aq. HCl / ethanol View Scheme
参考文献
Kishida,Y.; Nakamura,N.
Chemical and Pharmaceutical Bulletin, 1969 , vol. 17, p. 2424 - 2435
反应条件
1: (i) KOtBu, tBuOH, (ii) /BRN= 1904574/
2: H2 / PtO2 / ethanol
View Scheme
参考文献
Kishida,Y.; Nakamura,N.
Chemical and Pharmaceutical Bulletin, 1969 , vol. 17, p. 2424 - 2435
