6,7-二甲基-4a,5,8,8alpha-四氢萘-1,4-二酮合成路线 （共 6 条）
反应条件
methyltrioxorhenium (VII) in acetone 6 h; Ambient temperature;
参考文献
Zhu, Zuolin; Espenson, James H.
Journal of the American Chemical Society, 1997 , vol. 119, # 15 p. 3507 - 3512
反应条件
1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione in dimethyl sulfoxide
T=80 - 85°C;
参考文献
Kotha, Sambasivarao; Banerjee, Shaibal; Mandal, Kalyaneswar
Synlett, 2004 , # 11 p. 2043 - 2045
反应条件
triethylamine in chloroform
22 h; Ambient temperature;
参考文献
Fernandez, M. Pilar; Gonzalez, Beatriz; Pardo, Mercedes; Soto, Jose L.
Anales de Quimica, 1994 , vol. 90, # 7-8 p. 477 - 482
反应条件
1: manganese(IV) oxide / toluene / 3 h / |Inert atmosphere; |Schlenk technique
2: bromine / dichloromethane / |Inert atmosphere; |Schlenk technique
3: ammonium hydroxide / ethanol; water / 8 h / |Reflux; |Inert atmosphere
View Scheme
参考文献
Sullivan, David J.; Clerac, Rodolphe; Jennings, Michael; Lough, Alan J.; Preuss, Kathryn E.
Chemical Communications, 2012 , vol. 48, # 89 p. 10963 - 10965
反应条件
1: 50 percent / AcOH, Na2Cr2O7*2H2O, aq. H2SO4 / a) 80-90 deg C, 1 h, b) RT, 12 h
2: 92 percent / 60percent aq. HClO4 / 20 h / Ambient temperature
3: 15 percent / CrO3, AcOH / 12 h / Ambient temperature
4: 5percent aq. NaOH
View Scheme
参考文献
Farina, F.; Fernandez, E.; Gimeno, V.; Valderrama, J. A.
Anales de Quimica, 1995 , vol. 91, # 3-4 p. 220 - 229
反应条件
1: manganese(IV) oxide / toluene / 3 h / |Inert atmosphere; |Schlenk technique
2: bromine / dichloromethane / |Inert atmosphere; |Schlenk technique
View Scheme
参考文献
Sullivan, David J.; Clerac, Rodolphe; Jennings, Michael; Lough, Alan J.; Preuss, Kathryn E.
Chemical Communications, 2012 , vol. 48, # 89 p. 10963 - 10965
