二苯甲酮-2,3,4,5,6-d5合成路线 （共 5 条）
反应条件
1: benzene-d6 With AlCl3, aluminium chloride T=0°C; Friedel-Crafts acylation; 0.5 h; Inert atmosphere; 2: benzoyl chloride T=0 - 20°C; Friedel-Crafts acylation;
参考文献
Yu, Zhoujie; Wang, Wei; Chen, Liqin
Journal of Labelled Compounds and Radiopharmaceuticals, 2011 , vol. 54, # 7 p. 352 - 356
反应条件
pyridinium chlorochromate in dichloromethane T=20°C;
参考文献
Mo, Fanyang; Trzepkowski, Louis J.; Dong, Guangbin
Angewandte Chemie - International Edition, 2012 , vol. 51, # 52 p. 13075 - 13079
Angew. Chem., 2012 , vol. 124, # 52 p. 13252 - 13256,5
反应条件
1.1: magnesium / tetrahydrofuran; ethylene dibromide / 0.75 h / 0 - 60 °C 1.2: 0.5 h / 0 °C 2.1: pyridinium chlorochromate / dichloromethane / 20 °C View Scheme
参考文献
Mo, Fanyang; Trzepkowski, Louis J.; Dong, Guangbin
Angewandte Chemie - International Edition, 2012 , vol. 51, # 52 p. 13075 - 13079
Angew. Chem., 2012 , vol. 124, # 52 p. 13252 - 13256,5
反应条件
1.1: magnesium / tetrahydrofuran; ethylene dibromide / 0.75 h / 0 - 60 °C 1.2: 0.5 h / 0 °C 2.1: pyridinium chlorochromate / dichloromethane / 20 °C View Scheme
参考文献
Mo, Fanyang; Trzepkowski, Louis J.; Dong, Guangbin
Angewandte Chemie - International Edition, 2012 , vol. 51, # 52 p. 13075 - 13079
Angew. Chem., 2012 , vol. 124, # 52 p. 13252 - 13256,5
反应条件
in benzene-d6 Ambient temperatureIrradiation; Product distribution;
参考文献
Turro, Nicholas J.; Tung, Chen-Ho
Tetrahedron Letters, 1980 , vol. 21, # 45 p. 4321 - 4322
