hydrogenchloride; dimethylsulfide borane complex; diethylzinc; oxygen; zinc dibromide; zinc 1.) ether, 2 h at 0 deg C then 8 h at r.t., 2.) hexane, 30 min at 0 deg C then 15 min, 3.) THF, perfluorohexanes, -78 deg C, 4.) ether, 3 h; Yield given. Multistep reaction;
参考文献
Klement, Ingo; Luetjens, Henning; Knochel, Paul
Tetrahedron, 1997 , vol. 53, # 27 p. 9135 - 9144
potassium carbonate; sodium iodide in butanone 18 h; Heating;
参考文献
Fuller, Anne-Marie L.; Leigh, David A.; Lusby, Paul J.; Slawin, Alexandra M. Z.; Walker, D. Barney
Journal of the American Chemical Society, 2005 , vol. 127, # 36 p. 12612 - 12619
in diethyl ether; cyclohexane to 6-bromo-1-hexene (1.04 mmol) and 2 equiv. of Me3SnH in Et2O at 0°C added LDA (1.04 mmol, in cyclohexane) under Ar, react. time 20 min, quenched with water; analyzed by GLPC;
