phosphate buffer T=25°C; dissection of nucleophilic and general roles for the reaction of phosphate mono- and dianion; solvent kinetic isotope effect; reaction with D2O at 25 deg C; effect of various pH; Rate constantMechanism;

phosphate buffer T=25°C; dissection of nucleophilic and general roles for the reaction of phosphate mono- and dianion; solvent kinetic isotope effect; reaction with D2O at 25 deg C; effect of various pH; Rate constantMechanism;