triethylamine in benzene

in ethanol; water T=20°C; 6.16667 h;

1: 1-vinyloxycarbonylpiperazine With 2,2'-azo-bisisobutyronitrile; Merrifield SH resin; reduced by dithiothreitol in N,N-dimethyl-formamide T=80°C; Addition; 2: p-toluenesulfonyl chloride With pyridine Solid phase reaction; 3: With 1,8-diazabicyclo[5.4.0]undec-7-ene; 3-chloro-benzenecarboperoxoic acid in dichloromethane Oxidation; Elimination;

benzoic acid

1: N-ethyl-N,N-diisopropylamine / 1-methyl-pyrrolidin-2-one / 3 h / 0 - 20 °C 2: hydrogenchloride / 1,4-dioxane; dichloromethane / 16 h / 0 - 20 °C View Scheme

hydrogenchloride in water; dimethyl sulfoxide T=25°C; Kinetics;

potassium chloride in water; dimethyl sulfoxide T=25°C; Rate constant;