氯[二(五氟苯基)]硼烷合成路线 （共 31 条）
反应条件
in n-heptane T=-70 - 105°C;
参考文献
US6657027 B2, ;
Page column 15 ;
反应条件
in hexane byproducts: Me2SnCl2; Ar-atmosphere; stirring (room temp., 1 h), 120.0°C (48 h); evapn. (reduced pressure), subliming (Ar-atmosphere, 35°C, vac., 65°C);
参考文献
Parks, Daniel J.; Piers, Warren E.
Organometallics, 1998 , vol. 17, # 25 p. 5492 - 5503
反应条件
1: With n-butyllithium in hexane; pentane T=-70°C; 2: With boron trichloride in pentane T=-70°C;
参考文献
Macromolecules, , vol. 37, # 11 p. 4004 - 4007
反应条件
in neat (no solvent) pyrolysis at 220°C within 25 hours;;
参考文献
Chambers,R.D.; Chivers,T.
Journal of the Chemical Society, 1965 , p. 3933 - 3939
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Gmelin Handbook: F: PerFHalOrg.4, 3.1.3.3.1, page 119 - 119
反应条件
in hexane; toluene under N2; soln. of BCl3 (1.00 equiv) in hexanes added to soln. of (Cu(C6F5))4(η2-toluene)2 in toluene at -78 °C; mixt. stirred at -78°C for 1 h and then allowed to gradually warm to room temp.; products not sepd.; product distribution in supernatant estimated by (19)F-NMR spectroscopy;
参考文献
Journal of Organometallic Chemistry, , vol. 681, # 1-2 p. 134 - 142
反应条件
in dichloromethane under N2; soln. of C6F5Cu in CH2Cl2 added dropwise over 20 min to soln. of BCl3 (3 equiv) in CH2Cl2 at -78 °C; mixt. stirred at -78 °C for 1 h and then allowed to slowly warm to room temp. and stirred for 3 h; after filtration all volatiles slowly removed under high vac. first at -25 °C and subsequently over 3 h at 0 °C; crude product distd. under dynamic vac. at ca. 40 °C into cold trap (liq. N2); vac. transfer into storage flask;
参考文献
Sundararaman, Anand; Jaekle, Frieder
Journal of Organometallic Chemistry, 2003 , vol. 681, # 1-2 p. 134 - 142
反应条件
1: diethyl ether View Scheme
参考文献
Organometallics, , vol. 16, # 23 p. 4995 - 5005
参考文献
Inorganic Chemistry, , vol. 50, # 1 p. 336 - 344
参考文献
Inorganic Chemistry, , vol. 50, # 1 p. 336 - 344
参考文献
Journal of the Chemical Society, , p. 3933 - 3939
