氯[二(五氟苯基)]硼烷合成路线 （共 31 条）
反应条件
in toluene 2 equivs. of borane, stirring for 1 h at room temp.; filtration off of Cp2ZrCl2, evapn., sublimation (30-40°C, high vac.); NMR spectroscopy;
参考文献
Spence, Rupert E.V.H.; Piers, Warren E.; Sun, Yimin; Parvez, Masood; MacGillivray, Leonard R.; Zaworotko, Michael J.
Organometallics, 1998 , vol. 17, # 12 p. 2459 - 2469
反应条件
in benzene-d6 2 equivs. of borane; centrifugation, not sepd.; NMR spectroscopy;
参考文献
Spence, Rupert E.V.H.; Piers, Warren E.; Sun, Yimin; Parvez, Masood; MacGillivray, Leonard R.; Zaworotko, Michael J.
Organometallics, 1998 , vol. 17, # 12 p. 2459 - 2469
反应条件
in benzene-d6 byproducts: CH4, C6H5CH3; addn. of 2 equivs. of borane to dibenzylzirconocene, addn. of 2 equivs. of Cp2ZrHMe; not sepd.; NMR spectroscopy;
参考文献
Spence, Rupert E.V.H.; Piers, Warren E.; Sun, Yimin; Parvez, Masood; MacGillivray, Leonard R.; Zaworotko, Michael J.
Organometallics, 1998 , vol. 17, # 12 p. 2459 - 2469
反应条件
in not given hydrolysis in neutral or alkaline soln.;
参考文献
Gmelin Handbook: B: B-Verb.9, 6.2.5, page 292 - 302
反应条件
in deuterated toluene to soln. Pt(Ph3P)2(H2C=CH2) in toluene-d8 at room temp. was added soln. ClB(C6F5)2 in toluene-d8, after agitation, 24 h under inert atm.; identified by NMR;
参考文献
Dalton Transactions, , # 23 p. 4030 - 4037
反应条件
in deuterated toluene to soln. Pt(Ph3P)2(H2C=CH2) in toluene-d8 at room temp. was added soln. ClB(C6F5)2 in toluene-d8, after agitation, 24 h under inert atm.; identified by NMR;
参考文献
Dalton Transactions, , # 23 p. 4030 - 4037
参考文献
Liebigs Annalen der Chemie, , vol. 719, p. 169 - 186
B: B-Verb.9, 6.2.1, page 268 - 269
反应条件
in deuterated toluene to soln. Pt(Ph3P)2(H2C=CH2) in toluene-d8 at room temp. was added soln. ClB(C6F5)2 in toluene-d8, after agitation, 24 h under inert atm.; identified by NMR;
参考文献
Dalton Transactions, , # 23 p. 4030 - 4037
反应条件
in neat (no solvent) stirring (room temp., 1 h); filtering; elem. anal.;
参考文献
Parks, Daniel J.; Spence, Rupert E. Von H.; Piers, Warren E.
Angewandte Chemie (International Edition in English), 1995 , vol. 34, # 7 p. 809 - 811
反应条件
dimethylmono-chlorosilane 4 h;
参考文献
Schloegl, Martin; Riethmueller, Silke; Troll, Carsten; Moeller, Martin; Rieger, Bernhard
Macromolecules, 2004 , vol. 37, # 11 p. 4004 - 4007
