LiCl in diethyl ether (N2); the phenylene compd. (0.53 mol) and NaBH4 (0.27 mol) allowed to react for 55 h in a steel ball mill after adding diethyl ether and LiCl; (N2); all volatiles were removed (vac.); fractional distn. of the condensate;
参考文献
Maennig, Detlef; Noeth, Heinrich
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1985 , p. 1689 - 1692
→
反应条件
2 atm. of CO, 1 d at -10°C;
参考文献
Hartwig, John F.; Muhoro, Clare N.; He, Xiaoming; Eisenstein, Odile; Bosque, Ramon; Maseras, Feliu
Journal of the American Chemical Society, 1996 , vol. 118, # 44 p. 10936 - 10937
diborane in toluene T=55°C; 2 h; Inert atmosphere;
参考文献
Coleridge, Brian M.; Angert, Thomas P.; Marks, Lucas R.; Hamilton, Patrick N.; Sutton, Christopher P.; Matos, Karl; Burkhardt, Elizabeth R.
Tetrahedron Letters, 2010 , vol. 51, # 46 p. 5973 - 5976
→
反应条件
in deuterated toluene (inert atm.); sealed NMR tube (-5°C), temp. gradually raised (20°C, over 3 h); not isolated; determined by NMR;
参考文献
Lantero, Dean R.; Ward, Donald L.; Smith III, Milton R.
Journal of the American Chemical Society, 1997 , vol. 119, # 41 p. 9699 - 9708
Hartwig, John F.; Muhoro, Clare N.; He, Xiaoming; Eisenstein, Odile; Bosque, Ramon; Maseras, Feliu
Journal of the American Chemical Society, 1996 , vol. 118, # 44 p. 10936 - 10937
