1: With (R)-1,1'-bis(diphenylphosphino)-2,2'-binapthyl; [Rh(COD)2](1+)*BF4(1-) in ethylene glycol dimethyl ether T=-78 - 20°C; 2: With sodium hydroxide; dihydrogen peroxide in ethylene glycol dimethyl ether T=0 - 20°C; 2 h; Further stages. Title compound not separated from byproducts.;
参考文献
Ramachandran, P. Veeraraghavan; Jennings, Michael P.
Journal of Fluorine Chemistry, 2007 , vol. 128, # 7 p. 827 - 831
1: With [Rh(COD)(dppb)](1+)*BF4(1-) in tetrahydrofuran T=-25°C; 0.75 h; 2: With sodium hydroxide; dihydrogen peroxide in tetrahydrofuran Further stages. Title compound not separated from byproducts.;
参考文献
Ramachandran, P. Veeraraghavan; Jennings, Michael P.; Brown, Herbert C.
Organic Letters, 1999 , vol. 1, # 9 p. 1399 - 1402
1: With (R)-1,1'-bis(diphenylphosphino)-2,2'-binapthyl; [Rh(COD)2](1+)*BF4(1-) in ethylene glycol dimethyl ether T=-78 - 20°C; 2: With sodium hydroxide; dihydrogen peroxide in ethylene glycol dimethyl ether T=0 - 20°C; 2 h; Further stages. Title compound not separated from byproducts.;
参考文献
Ramachandran, P. Veeraraghavan; Jennings, Michael P.
Journal of Fluorine Chemistry, 2007 , vol. 128, # 7 p. 827 - 831
Ti(OCH(CH3)2)4 in neat (no solvent) under Ar, addn. of 1.5 equiv. of catecholborane to mixt. of 1.0 equiv. decene and 0.1 equiv. Ti(OCH(CH3)2)4, stirred for 12 h; not isolated, identified by (11)B-NMR spectroscopy;
参考文献
Burgess, Kevin; Donk, Wilfed A. van der
Organometallics, 1994 , vol. 13, p. 3616 - 3620
1: With (4R,5R)-DIOP; [{RhCl(cod)}2] in tetrahydrofuran T=20°C; 4 h; 2: With sodium hydroxide; dihydrogen peroxide in tetrahydrofuran; water optical yield given as percent ee;
参考文献
Marques, Carolina S.; Burke, Anthony J.
Synthetic Communications, 2008 , vol. 38, # 23 p. 4207 - 4214
Ti(OCH(CH3)2)4 in neat (no solvent)
under Ar, addn. of 1.5 equiv. of catecholborane to mixt. of 1.0 equiv. cyclohexene and 0.1 equiv. Ti(OCH(CH3)2)4, stirred for 12 h; not isolated, identified by (11)B-NMR spectroscopy;
参考文献
Burgess, Kevin; Donk, Wilfed A. van der
Organometallics, 1994 , vol. 13, p. 3616 - 3620
