RhCl(PPh3)3 in THF-d8 (tetrahydrofuran-d8)
T=20°C; 5 h; Title compound not separated from byproducts;
参考文献
Hamilton, Michael G.; Hughes, Catrin E.; Irving, Alison M.; Vogels, Christopher M.; Westcott, Stephen A.
Journal of Organometallic Chemistry, 2003 , vol. 680, # 1-2 p. 143 - 147
P(C6H5)3 in THF-d8 (tetrahydrofuran-d8)
addn. of 3 equiv. of PPh3 and catecholborane to soln. of Rh-complex (25°C, (11)B-NMR monitoring); not isolated;
参考文献
Burgess, Kevin; Van Der Donk, Wilfred A.; Westcott, Stephen A.; Marder, Todd B.; Baker, R. Thomas; Calabrese, Joseph C.
Journal of the American Chemical Society, 1992 , vol. 114, # 24 p. 9350 - 9359
Wilkinson's catalyst in benzene-d6
addn. of a soln. of boron compd. in C6D6 to a soln. of thioketone and rhodium complex in C6D6; not isolated, detected by NMR;
参考文献
Carter, Charles A.G.; Vogels, Christopher M.; Harrison, Daniel J.; Karen; Gagnon; Norman, David W.; Langler, Richard F.; Baker, R. Thomas; Westcott, Stephen A.
Organometallics, 2001 , vol. 20, # 11 p. 2130 - 2132
in THF-d8 (tetrahydrofuran-d8)
byproducts: P(C6H5)3; addn. of soln. of catecholborane to soln. of Rh-complex and oct-1-ene (-78°C, NMR tube), warming (-40°C, (31)P-NMR monitoring), warming to 25°C; (11)B-NMR spectroscopy;
参考文献
Burgess, Kevin; Van Der Donk, Wilfred A.; Westcott, Stephen A.; Marder, Todd B.; Baker, R. Thomas; Calabrese, Joseph C.
Journal of the American Chemical Society, 1992 , vol. 114, # 24 p. 9350 - 9359
in dichloromethane-d2
byproducts: H2, P(C6H5)3; dropwise addn. of soln. of catecholborane to soln. of Rh-complex; not isolated; (1)H-, (11)B- and (31)P-NMR spectroscopy; further products;
参考文献
Burgess, Kevin; Van Der Donk, Wilfred A.; Westcott, Stephen A.; Marder, Todd B.; Baker, R. Thomas; Calabrese, Joseph C.
Journal of the American Chemical Society, 1992 , vol. 114, # 24 p. 9350 - 9359
