in THF-d8 (tetrahydrofuran-d8)
(N2); dropwise addn. of catecholborane soln. to a soln. of the Rh-complex; stirring for 30 min; (1)H-; (31)P-; (11)B-NMR;
参考文献
Westcott, Stephen A.; Blom, Henk P.; Marder, Todd B.; Baker, R. Thomas; Calabrese, Joseph C.
Inorganic Chemistry, 1993 , vol. 32, p. 2175 - 2182
water
byproducts: H2, catechol; equiv. amt. of catecholborane added to alkyne under N2, heated to 70°C for 3 h, large excess of water added, stirred overnight; filtered, washed with copious amts. of water;
参考文献
Kabalka, George W.; Gooch, E. Eugene; Hsu, Henry C.
Synthetic Communications, 1981 , vol. 11, # 3 p. 247 - 252
