3-甲基-2-环戊烯-1-酮合成路线 （共 109 条）
反应条件
1: imidazole / Heating 2: 67 percent / diethyl ether / 3.5 h View Scheme
参考文献
Mironov,V.A. et al.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1973 , vol. 22, p. 570 - 573
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1973 , vol. 22, # 3 p. 596 - 599
反应条件
1: HCl / ethanol / 0 - 25 °C 2: 1.) p-TsOH; 2.) m-CPBA / 1.) C6H6, reflux; 2.) CH2Cl2, 0 deg C to room temp. 3: 96 percent / K2CO3 / acetone / Heating 4: 60 percent / NaH, KH / dimethylsulfoxide / 24 h / 20 - 30 °C 5: p-TsOH*Py / acetone; H2O / 10 h / Heating View Scheme
参考文献
Matsuyama, Haruo; Miyazawa, Yasuyuki; Kobayashi, Michio
Chemistry Letters, 1986 , p. 433 - 436
反应条件
1: 1.) p-TsOH; 2.) m-CPBA / 1.) C6H6, reflux; 2.) CH2Cl2, 0 deg C to room temp. 2: 96 percent / K2CO3 / acetone / Heating 3: 60 percent / NaH, KH / dimethylsulfoxide / 24 h / 20 - 30 °C 4: p-TsOH*Py / acetone; H2O / 10 h / Heating View Scheme
参考文献
Matsuyama, Haruo; Miyazawa, Yasuyuki; Kobayashi, Michio
Chemistry Letters, 1986 , p. 433 - 436
反应条件
1: 96 percent / K2CO3 / acetone / Heating 2: 60 percent / NaH, KH / dimethylsulfoxide / 24 h / 20 - 30 °C 3: p-TsOH*Py / acetone; H2O / 10 h / Heating View Scheme
参考文献
Matsuyama, Haruo; Miyazawa, Yasuyuki; Kobayashi, Michio
Chemistry Letters, 1986 , p. 433 - 436
反应条件
1: 60 percent / NaH, KH / dimethylsulfoxide / 24 h / 20 - 30 °C 2: p-TsOH*Py / acetone; H2O / 10 h / Heating View Scheme
参考文献
Matsuyama, Haruo; Miyazawa, Yasuyuki; Kobayashi, Michio
Chemistry Letters, 1986 , p. 433 - 436
参考文献
Conia,J.-M.; Leriverend,M.-L.
Bulletin de la Societe Chimique de France, 1970 , p. 2981 - 2991
反应条件
pyridinium p-toluenesulfonate in water; acetone 10 h; Heating; Yield given. Yields of byproduct given;
参考文献
Matsuyama, Haruo; Miyazawa, Yasuyuki; Kobayashi, Michio
Chemistry Letters, 1986 , p. 433 - 436
反应条件
1: H2 / Ni 2: TsOH View Scheme
参考文献
Mironov,V.A. et al.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1973 , vol. 22, p. 570 - 573
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1973 , vol. 22, # 3 p. 596 - 599
反应条件
1: (i) CH3CO3H, Na2CO3, (ii) H2O, (iii) CrO3, aq. H2SO4 2: H2 / Ni 3: TsOH View Scheme
参考文献
Mironov,V.A. et al.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1973 , vol. 22, p. 570 - 573
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1973 , vol. 22, # 3 p. 596 - 599
反应条件
1: KOAc / dimethylformamide 2: (i) LiAlH4, (ii) H2Cr2O7 View Scheme
参考文献
Julia,M.; Colomer,E.
Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques, 1970 , vol. 270, p. 1305 - 1307
