3-甲基-2-环戊烯-1-酮合成路线 （共 109 条）
反应条件
1: (i) aq. NaOH, EtOH, (ii) /BRN= 102415/ 2: (i) BF3-Et2O, (ii) aq. HCl View Scheme
参考文献
Smith,A.B. et al.
Tetrahedron Letters, 1975 , p. 4225 - 4228
反应条件
(i) LiAlH4, (ii) H2Cr2O7; Multistep reaction;
参考文献
Julia,M.; Colomer,E.
Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques, 1970 , vol. 270, p. 1305 - 1307
参考文献
Traverso,G. et al.
Gazzetta Chimica Italiana, 1971 , vol. 101, p. 225 - 244
反应条件
1: (i) NaH, Et2O, (ii) /BRN= 471433/ 2: (i) CuI, Et2O, (ii) /BRN= 2418288/ View Scheme
参考文献
Sum,F.-W.; Weiler,L.
Canadian Journal of Chemistry, 1979 , vol. 57, p. 1431 - 1441
反应条件
(i) CuI, Et2O, (ii) /BRN= 2418288/; Multistep reaction;
参考文献
Sum,F.-W.; Weiler,L.
Canadian Journal of Chemistry, 1979 , vol. 57, p. 1431 - 1441
参考文献
Mironov,V.A. et al.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1973 , vol. 22, p. 570 - 573
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1973 , vol. 22, # 3 p. 596 - 599
反应条件
1: 2: Pummerer Sulfoxide Rearrangement; 5 h; Reflux; Temperature;
参考文献
Mikina, Maciej
Phosphorus, Sulfur and Silicon and the Related Elements, 2013 , vol. 188, # 4 p. 454 - 458
参考文献
Godchot; Taboury
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1913 , vol. 156, p. 1779 Anm. 2
Bulletin de la Societe Chimique de France, 1913 , vol. <4> 13, p. 592
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; chloro-trimethyl-silane; copper(I) bromide dimethylsulfide complex 1) THF, -78 deg C, 1 h, 2) THF, 2.1) -78 deg C, 6 h, 2.2) -45 deg C, 2 h; Yield given. Multistep reaction;
参考文献
Piers; Renaud
Synthesis, 1992 , # 1-2 p. 74 - 82
反应条件
1: 56 percent / Br2, Et3N / CCl4 / 1.) 0 deg C, 5 min, 2.) RT, 1.75 h 2: 89 percent / TsOH / benzene / 63 h / Heating; azeotropic removal of water View Scheme
参考文献
Journal of Organic Chemistry, , vol. 47, # 10 p. 1855 - 1869
