in benzene byproducts: propylene, 1-butene, propane; silyl ether added to Ru complex in benzene, stirred at 80°C under vac. for 1 d; volatiles sepd. by trap to trap distn., anlyzed by gas chromy.; solid recrystd., analyzed by IR;
in benzene silyl ether added to Ru complex in benzene, stirred at 80°C under vac. for 3 h; volatiles sepd. by trap to trap distn., anlyzed by gas chromy.; solid recrystd., analyzed by IR;
in neat (no solvent) educts mixed at in vac., kept at -20°C and stirred for 2 h; evapd. in vac., solid washed with Et2O and hexane, dissolved in toluene, filtered, concd. in vac., ppt. filtered, washed with hexane, dried in vac.;
参考文献
Ito, Takashi; Horino, Hiroshi; Koshiro, Yoshitaka; Yamamoto, Akio
Bulletin of the Chemical Society of Japan, 1982 , vol. 55, # 2 p. 504 - 512
