2-(1-金刚烷)-1-苯乙酮合成路线 （共 12 条）
反应条件
potassium tert-butylate; FeBr2 in dimethyl sulfoxide
T=60°C; 0.5 h;
参考文献
Nazareno, Monica A.; Rossi, Roberto A.
Journal of Organic Chemistry, 1996 , vol. 61, # 5 p. 1645 - 1649
反应条件
boron trifluoride diethyl etherate in dichloromethane
T=20°C; Friedel-Crafts type alkylation; 4 h;
参考文献
Aoyama, Motoshi; Hara, Shoji
Tetrahedron, 2009 , vol. 65, # 18 p. 3682 - 3687
反应条件
tetraethylammonium iodide in N,N-dimethyl-formamide
T=0 - 10°C; Acylation; Electrochemical reaction;
参考文献
Rakhimov; Cherepanov
Russian Journal of Organic Chemistry, 1999 , vol. 35, # 9 p. 1393 - 1394
反应条件
di-tert-amyl peroxide in octane
Heating;
参考文献
Cai, Yudong; Roberts, Brian P.; Tocher, Derek A.; Barnett, Sarah A.
Organic and Biomolecular Chemistry, 2004 , vol. 2, # 17 p. 2517 - 2529
反应条件
2,2,6,6-tetramethyl-piperidine; di-tert-amyl peroxide in octane
Heating;
参考文献
Cai, Yudong; Roberts, Brian P.; Tocher, Derek A.; Barnett, Sarah A.
Organic and Biomolecular Chemistry, 2004 , vol. 2, # 17 p. 2517 - 2529
反应条件
2,2,6,6-tetramethyl-piperidine; di-tert-amyl peroxide in octane
3 h; Heating;
参考文献
Cai, Yudong; Roberts, Brian P.; Tocher, Derek A.; Barnett, Sarah A.
Organic and Biomolecular Chemistry, 2004 , vol. 2, # 17 p. 2517 - 2529
反应条件
2,2,6,6-tetramethyl-piperidine; di-tert-amyl peroxide in octane
4 h; Heating;
参考文献
Cai, Yudong; Roberts, Brian P.; Tocher, Derek A.; Barnett, Sarah A.
Organic and Biomolecular Chemistry, 2004 , vol. 2, # 17 p. 2517 - 2529
反应条件
1.1: iodine; mercuric oxide / diethyl ether / 3 h / 20 °C
1.2: t-BuOK / diethyl ether; tetrahydrofuran / 20 °C
2.1: 2,2,6,6-tetramethylpiperidine; di-tert-amyl peroxide / octane / 4 h / Heating
View Scheme
参考文献
Cai, Yudong; Roberts, Brian P.; Tocher, Derek A.; Barnett, Sarah A.
Organic and Biomolecular Chemistry, 2004 , vol. 2, # 17 p. 2517 - 2529
反应条件
copper(l) chloride; lithium chloride in tetrahydrofuran; diethyl ether
T=0°C;
参考文献
Vicha, Robert; Rouchal, Michal; Kozubkova, Zuzana; Kurritka, Ivo; Marek, Radek; Branna, Petra; Cmelik, Richard
Supramolecular Chemistry, 2011 , vol. 23, # 10 p. 663 - 677
反应条件
sulfuric acid in tetrachloromethane
T=5°C; 0.25 h;
参考文献
Kell,D.R.; McQuillin,F.J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1972 , p. 2100 - 2103
