in gas Kinetics; byproducts: SiF3I; gas phase pyrolysis at 603-652 K (various conditions, addn. of Ar or SiF4); monitored by spectrophotometry, product identification by IR and mass spectroscopy;
参考文献
Bains, Swroop K.; Noble, Paul N.; Walsh, Robin
Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1986 , vol. 82, p. 837 - 848
in neat (no solvent) reaction with SiF2; determination by MS and NMR; further products;; main product is CF3SiF2I;;
参考文献
Margrave, J. L.; Sharp, K. G.; Wilson, P. W.
Journal of Inorganic and Nuclear Chemistry, 1970 , vol. 32, p. 1817 - 1825
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Gmelin Handbook: C: MVol.D2, 4.2.4.4.7, page 322 - 323
in neat (no solvent) The halogen was co-condensed in a flask at -196°C with the mixt. of SiF4 and SiF2 emerging out of the reactor tube;; evapd.,; the volatile products were sepd. and detected by NMR and MS;;
参考文献
Suresh, Bettadapura S.; Thompson, James Charlton
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1987 , p. 1123 - 1126
