1: With [{(η5-C5Me5)IrCl}2(μ-Cl)2]; [Ru2(p-PriC6H4Me)2(μ-Cl)Cl]2 in neat (no solvent)
T=130°C; 3 h; Inert atmosphereSchlenk techniqueGreen chemistry;
2: With potassium tert-butylate in neat (no solvent)
T=150°C; 12 h; Inert atmosphereSchlenk techniqueGreen chemistry;
1: With manganese(IV) oxide; polymer-bound trimethyl ammonium cyanoborohydride; 4 A molecular sieve in dichloromethane
Heating;
2: With acetic acid
Heating; Further stages.;
参考文献
Blackburn, Leonie; Taylor, Richard J. K.
Organic Letters, 2001 , vol. 3, # 11 p. 1637 - 1639
