in tetrahydrofuran; biphenyl; pentane T=-75.16°C; Inert atmosphere; Equilibrium constant;

in tetrahydrofuran; biphenyl; pentane T=-75.16°C; Inert atmosphere; Equilibrium constant;

暂无反应条件数据

1: 70 percent / diethyl ether / -30 °C 2: NH3, Na / 4 h / -78 °C View Scheme

triethyloxonium tetra-fluoroborate 1.) Et2O, -60 - -50 deg C; 2.) H2O, 0 deg C; Yield given. Multistep reaction;

1: in tetrahydrofuran T=-30°C; 1 h; 2: With hydrogenchloride; water in tetrahydrofuran pH=6.3;

暂无反应条件数据

in diethyl ether byproducts: (p-CF3C6H4)CO(C2H5); N2-atmosphere; dropwise addn. of 2 equiv. of Li-compd. to Fe-complex soln. at -65°C, stirring for 5 h, evapn. (-50 to -40°C, vac.), addn. of Et3OBF4, dissoln. in H2O at 0°C, layering with petroleum ether, addn. of Et3OBF4; extn. into petroleum ether, drying (Na2SO4), solvent removal (vac.), chromy. (Al2O3, petroleum ether, then petroleum ether/Et2O=20:1), solvent removal (vac.), recrystn. (petroleum ether, -80°C); elem. anal.;

TeCl4 in diethyl ether; hexane T=-78 - 25°C; 4.5 h;

hydrogenchloride; TeCl4 in diethyl ether; hexane T=-78°C; multistep reaction; other temperature, reagent; Product distribution;