(±)-4-氯苯乙烯环氧化物合成路线 （共 77 条）
反应条件
sodium tetrahydroborate; ethanol T=20 - 40°C;
参考文献
INTERVET INTERNATIONAL B.V.; BRINK, Monika; NIEDERMANN, Hans-Peter; KNELL, Marcus; FENG, Tao; TRZASKA, Scott, T.; COOPER, Arthur, J.; DESAI, Shaileshkumar Ramanlal; GORE, Vinayak Keshav
Patent: WO2012/85645 A1, 2012 ;
Location in patent: Page/Page column 36 ;
反应条件
in 1,2-dichloro-ethane T=60°C; 3 h;
参考文献
Forbes, David C.; Standen, Michael C.; Lewis, Derrick L.
Organic Letters, 2003 , vol. 5, # 13 p. 2283 - 2286
反应条件
sodium hydride in tetrahydrofuran; dimethyl sulfoxide
参考文献
Choi, Matthew Kwok Wai; Toy, Patrick H.
Tetrahedron, 2004 , vol. 60, # 12 p. 2875 - 2879
反应条件
iodosylbenzene; 1-butylpyridinium tetrafluoroborate; [MnIIIT(N-Me-4-Py)P][PF6]5 T=30°C; 4 h; in open air; Title compound not separated from byproducts.;
参考文献
Saha, Rajat; Joarder, Biplab; Roy, Anupam Singha; Manirul Islam, Sk.; Kumar, Sanjay
Chemistry - A European Journal, 2013 , vol. 19, # 49 p. 16607 - 16614
反应条件
Oxonereg;; C16H22Cl2FeN4(2+); sodium hydrogencarbonate in water; acetonitrile T=20°C; 0.0833333 h;
参考文献
Chow, Toby Wai-Shan; Wong, Ella Lai-Ming; Guo, Zhen; Liu, Yungen; Huang, Jie-Sheng; Che, Chi-Ming
Journal of the American Chemical Society, 2010 , vol. 132, # 38 p. 13229 - 13239
反应条件
water; C-200 (barium hydroxide) in acetonitrile 1.5 h; Heating;
参考文献
Sinisterra, J. V.; Marinas, J. M.; Riquelme, F.; Arias, M. S.
Tetrahedron, 1988 , vol. 44, # 5 p. 1431 - 1440
反应条件
sodium hypochlorite; potassium bromide in phosphate buffer; acetonitrile T=40°C; pH=10.4; 1 h;
参考文献
Klawonn, Markus; Bhor, Santosh; Mehltretter, Gerald; Doebler, Christian; Fischer, Christine; Beller, Matthias
Advanced Synthesis and Catalysis, 2003 , vol. 345, # 3 p. 389 - 392
反应条件
18-crown-6 ether; carbon dioxide in N,N-dimethyl-formamide T=15 - 20°C; 20 h;
参考文献
Yamamoto, Hiroshi; Mashino, Tadahiko; Nagano, Tetsuo; Hirobe, Masaaki
Tetrahedron Letters, 1989 , vol. 30, # 31 p. 4133 - 4136
反应条件
sodium methylate 1.) CH3CN; Multistep reaction;
参考文献
Spelberg, Jeffrey H. Lutje; Van Vlieg, Johan E. T. Hylckama; Tang, Lixia; Janssen, Dick B.; Kellogg, Richard M.
Organic Letters, 2001 , vol. 3, # 1 p. 41 - 43
反应条件
methyltrioxorhenium (VII); (S,S)-Ph-pybox in dichloromethane T=20°C; 19 h; chemoselective reaction;
参考文献
Kiersch, Konstanze; Li, Yuehui; Junge, Kathrin; Szesni, Normen; Fischer, Richard; Kuehn, Fritz E.; Beller, Matthias
European Journal of Inorganic Chemistry, 2012 , # 36 p. 5972 - 5978
