(±)-4-氯苯乙烯环氧化物合成路线 （共 77 条）
反应条件
in tetrahydrofuran; dimethyl sulfoxide 1) -5 to -10 deg C, 15 min; 2) 2 h, r.t.;
参考文献
Krug, Reinhard; Jugelt, Werner
Zeitschrift fuer Chemie (Stuttgart, Germany), 1981 , vol. 21, # 11 p. 406 - 407
反应条件
sodium hydroxide in water T=25°C; 5.5 h;
参考文献
Patil, Rajendra D.; Adimurthy, Subbarayappa; Ranu, Brindaban C.
Synthetic Communications, 2010 , vol. 40, # 21 p. 3233 - 3239
反应条件
1-methyl-1H-imidazole; FeCl3·6H2O; dihydrogen peroxide in water; acetone T=25 - 62°C; In air; chemoselective reaction;
参考文献
Hasan, Kamrul; Brown, Nicole; Kozak, Christopher M.
Green Chemistry, 2011 , vol. 13, # 5 p. 1230 - 1237
反应条件
pyridine-2,6-dicarboxylic acid; FeCl3·6H2O; N1,N1-Dimethyl-N2-cyclohexylformamidine; dihydrogen peroxide in 1,1-dimethylpropan-1-ol; water T=20°C; 1 h; Air; chemoselective reaction;
参考文献
Schroeder, Kristin; Enthaler, Stephan; Join, Benoit; Junge, Kathrin; Beller, Matthias
Advanced Synthesis and Catalysis, 2010 , vol. 352, # 10 p. 1771 - 1778
反应条件
pyridine-2,6-dicarboxylic acid; FeCl3·6H2O; N1,N1-Dimethyl-N2-cyclohexylformamidine; dihydrogen peroxide in 1,1-dimethylpropan-1-ol; water T=20°C; 1 h; Air; chemoselective reaction;
参考文献
Schroeder, Kristin; Enthaler, Stephan; Join, Benoit; Junge, Kathrin; Beller, Matthias
Advanced Synthesis and Catalysis, 2010 , vol. 352, # 10 p. 1771 - 1778
反应条件
sodium hydroxide in dichloromethane
参考文献
Lutje Spelberg, Jeffrey H.; Rink, Rick; Kellogg, Richard M.; Janssen, Dick B.
Tetrahedron Asymmetry, 1998 , vol. 9, # 3 p. 459 - 466
反应条件
methanol; sodium methylate
参考文献
Spaeth
Monatshefte fuer Chemie, 1915 , vol. 36, p. 6
反应条件
2,2,6,6-tetramethylpiperidinyl-lithium 1.) THF, -70 deg C, 30 min, 2.) THF, -78 deg C to room temperature; Yield given. Multistep reaction;
参考文献
Shi, Li-Lan; Zhou, Zhang-Lin; Huang, Yao-Zeng
Tetrahedron Letters, 1990 , vol. 31, # 29 p. 4173 - 4174
参考文献
Spaeth
Monatshefte fuer Chemie, 1915 , vol. 36, p. 6
反应条件
competition reaction; epoxidation by 3-CPBA or PBA and different Co(II) complexes;
参考文献
Brook, M. Andrew; Smith, John R. Lindsay; Higgins, Raymond; Lester, David
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1985 , p. 1049 - 1056
