(±)-4-氯苯乙烯环氧化物合成路线 (共 77 条)
反应条件
1,8-diazabicyclo[5.4.0]undec-7-ene in dichloromethane Heating; Product distribution;
参考文献
Chemistry Letters, , p. 333 - 336
反应条件
Amberlite IRA-400; borohydride form; copper(II) sulfate in methanol T=20°C; Reduction; 1 h;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 70, # 5 p. 1101 - 1107
反应条件
diphosphorous tetraiodide; tetraethylammonium bromide; water in dichloromethane T=20°C; 6 h; regioselective reaction;
参考文献
Telvekar, Vikas N.; Rane, Rajesh A.
Synthetic Communications, 2010 , vol. 40, # 14 p. 2108 - 2112
反应条件
diphosphorous tetraiodide; tetraethylammonium bromide; water in dichloromethane T=20°C; 6 h; regioselective reaction;
参考文献
Telvekar, Vikas N.; Rane, Rajesh A.
Synthetic Communications, 2010 , vol. 40, # 14 p. 2108 - 2112
反应条件
sodium tetrahydroborate; β-cyclodextrin in water T=20°C; 67 h;
参考文献
Bulletin de la Societe Chimique de France, , vol. 133, # 2 p. 161 - 166
反应条件
1: With zinc trifluoromethanesulfonate T=20°C; 1 h; Inert atmosphere; 2: With 1,1'-bis-(diphenylphosphino)ferrocene; tri-ruthenium(0)dodecacarbonyl; toluene-4-sulfonic acid in 1,4-dioxane T=150°C; 22 h; Inert atmosphere; regioselective reaction;
参考文献
Chemistry - A European Journal, , vol. 20, # 7 p. 1818 - 1824
反应条件
carbon monoxide in tetrahydrofuran; water T=110°C; P=6840.46 Torr; 2 h; Autoclave; chemoselective reaction;
参考文献
Mikami, Yusuke; Noujima, Akifumi; Mitsudome, Takato; Mizugaki, Tomoo; Jitsukawa, Koichiro; Kaneda, Kiyotomi
Tetrahedron Letters, 2010 , vol. 51, # 41 p. 5466 - 5468
反应条件
[ReO2I(PPh3)2] in acetonitrile 24 h; Reflux;
参考文献
Tetrahedron Letters, , vol. 52, # 51 p. 6960 - 6962
反应条件
1: 4-chlorostyrene oxide With sec.-butyllithium in tetrahydrofuran; hexane; cyclohexane T=-58°C; 0.000206667 h; flow microreactor; 2: methyl iodide in tetrahydrofuran; hexane; cyclohexane T=-58°C; 0.000555556 h; flow microreactor;
参考文献
Nagaki, Aiichiro; Takizawa, Eiji; Yoshida, Jun-Ichi
Chemistry - A European Journal, 2010 , vol. 16, # 47 p. 14149 - 14158
反应条件
(S,S)-[1,2-cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]cobaltIII*OAc; water in tetrahydrofuran T=0 - 20°C; 48 h;
参考文献
Schaus, Scott E.; Brandes, Bridget D.; Larrow, Jay F.; Tokunaga, Makoto; Hansen, Karl B.; Gould, Alexandra E.; Furrow, Michael E.; Jacobsen, Eric N.
Journal of the American Chemical Society, 2002 , vol. 124, # 7 p. 1307 - 1315