(±)-4-氯苯乙烯环氧化物合成路线 (共 77 条)
反应条件
sodium hydroxide; sodium phosphate buffer; Aspergillus niger epoxide hydrolase T=0°C; pH=7; KineticsProduct distribution; Further Variations:Reagents;
参考文献
Moussou; Archelas; Baratti; Furstoss
Journal of Organic Chemistry, 1998 , vol. 63, # 11 p. 3532 - 3537
反应条件
1: With Solanum tuberosum Epoxide Hydrolase in water T=0°C; pH=6.7; 25 h; 2: With Aspergillus niger epoxide hydrolase in water pH=7.1; 45 h;
参考文献
Manoj; Archelas; Baratti; Furstoss
Tetrahedron, 2001 , vol. 57, # 4 p. 695 - 701
反应条件
Aspergillus niger CGMCC 0496 in phosphate buffer; N,N-dimethyl-formamide T=25°C; pH=8.0; 1 h; Title compound not separated from byproducts.;
参考文献
Jin, Hao; Li, Zu-Yi; Dong, Xiao-Wei
Organic and Biomolecular Chemistry, 2004 , vol. 2, # 3 p. 408 - 414
参考文献
Kim, Sang Kyun; Jacobsen, Eric N.
Angewandte Chemie - International Edition, 2004 , vol. 43, # 30 p. 3952 - 3954
反应条件
aluminum oxide; sodium tetrahydroborate; palladium dichloride in hexane; water T=30°C; 1 h;
参考文献
Synthetic Communications, , vol. 40, # 9 p. 1339 - 1344
反应条件
sodium dihydroperiodate; sulfuric acid in water T=20°C; 0.333333 h;
参考文献
Telvekar, Vikas N.; Patel, Dharmeshkumar J.; Mishra, Sanket J.
Synthetic Communications, 2009 , vol. 39, # 2 p. 311 - 315
反应条件
[ReO2I(PPh3)2] in acetonitrile 24 h; Reflux;
参考文献
Tetrahedron Letters, , vol. 52, # 51 p. 6960 - 6962
反应条件
ammonium hydroxide
microwave irradiation;
参考文献
Sello, Guido; Orsini, Fulvia; Bernasconi, Silvana; Gennaro, Patrizia Di
Tetrahedron Asymmetry, 2006 , vol. 17, # 3 p. 372 - 376
反应条件
potassium tert-butylate in tert-butyl alcohol
144 h; Heating;
参考文献
Okuma, Kentaro; Nishimura, Kenshin; Ohta, Hiroshi
Chemistry Letters, 1984 , p. 93 - 96
反应条件
iodine; aminopropyl silica gel in water; acetonitrile
T=25°C; 0.75 h;
参考文献
Tamami; Iranpoor; Mahdavi
Synthetic Communications, 2002 , vol. 32, # 8 p. 1251 - 1258