四(五氟苯基)-硼酸锂(1:1)合成路线 （共 7 条）
反应条件
n-butyllithium; carbon dioxide; boron trichloride in hexane; water; pentane
参考文献
Rhone-Poulenc Chimie
Patent: US5468902 A1, 1995 ;
反应条件
tert.-butyl lithium in diethyl ether; toluene; pentane
参考文献
Tosoh Akzo Corporation
Patent: US5493056 A1, 1996 ;
反应条件
sec.-butyllithium in octane; hexane
参考文献
Tosoh Akzo Corporation
Patent: US5493056 A1, 1996 ;
反应条件
boron trichloride in hexane
参考文献
Hijazi, Ahmed K.; Hmaideen, Akef Al; Syukri, Syukri; Radhakrishnan, Narayanan; Herdtweck, Eberhardt; Voit, Brigitte; Kuehn, Fritz E.
European Journal of Inorganic Chemistry, 2008 , # 18 p. 2892 - 2898
反应条件
1: 1-bromo-2,3,4,5,6-pentafluorobenzene With n-butyllithium in pentane T=-80°C; 0.583333 h; Inert atmosphere; 2: tris(pentafluorophenyl)-borane in pentane T=-80 - 20°C; 1.08333 h; Inert atmosphere;
参考文献
Kuprat, Marcus; Lehmann, Mathias; Schulz, Axel; Villinger, Alexander
Organometallics, 2010 , vol. 29, # 6 p. 1421 - 1427
反应条件
in pentane (Ar); addn. of a soln. of lithium compd. to a suspn. of boron compd. in pentane at -40°C, stirring overnight at room temp.; filtration, washing with pentane, drying in vac.;
参考文献
Alberti, Davide; Poerschke, Klaus-Richard
Organometallics, 2004 , vol. 23, # 6 p. 1459 - 1460
反应条件
in neat (no solvent) (Ar); at -78°C; solid collected, extd. (toluene), recrystd. (fractional, toluene, two-fold);
参考文献
Kleigrewe, Nina; Steffen, Winfried; Bloemker, Tobias; Kehr, Gerald; Froehlich, Roland; Wibbeling, Birgit; Erker, Gerhard; Wasilke, Julia-Christina; Wu, Guang; Bazan, Guillermo C.
Journal of the American Chemical Society, 2005 , vol. 127, # 40 p. 13955 - 13968
