1,1-二氯-2,3,3,3-四氟-1-丙烯合成路线 （共 28 条）
反应条件
anhydrous potassium sulfate; hydrogen; potassium hydroxide; 5 Pd(II)/C(eggshell)
T=1 - 8°C; 27 h; Autoclave;
参考文献
DAIKIN INDUSTRIES, LTD.; NOSE, Masatoshi; SUZUKI, Atsushi; SUGIYAMA, Akinari
Patent: WO2010/13576 A1, 2010 ;
Location in patent: Page/Page column 8-9 ;
反应条件
hydrogen; 0.5percent Pd/Al2O3 treated with hydrogen at 150-300C and fluorinated with HF at 150-250C
T=200°C; P=760.051 Torr; 0.00833333 h;
参考文献
Asahi Glass Company Limited
Patent: EP2371793 A1, 2011 ;
Location in patent: Page/Page column 12 ;
反应条件
hydrogen; 5 Pd/C
T=80 - 90°C; Product distribution / selectivity;
参考文献
ASAHI GLASS COMPANY, LIMITED
Patent: US2011/319680 A1, 2011 ;
Location in patent: Page/Page column 4-5 ;
反应条件
hydrogen; 0.5percent Pd/Al2O3 fluorinated by HF
T=200°C; Product distribution / selectivity;
参考文献
E. I. DU PONT DE NEMOURS AND COMPANY
Patent: WO2008/79265 A1, 2008 ;
Location in patent: Page/Page column 17-18 ;
反应条件
hydrogen fluoride; metal oxide catalyst with 95atom percent chromium and 5atom percent zinc prepared by co-precipitation of zinc and chromium hydroxides, calcined at 900C, treated with HF at 175-400C
T=300°C; P=760.051 Torr; 0.00833333 h;
参考文献
E. I. DU PONT DE NEMOURS AND COMPANY
Patent: WO2008/60612 A2, 2008 ;
Location in patent: Page/Page column 17 ;
反应条件
hydrogen; 0.5percent Pd/Al2O3 fluorinated by HF
T=200°C; Product distribution / selectivity;
参考文献
E. I. DU PONT DE NEMOURS AND COMPANY
Patent: WO2008/79265 A1, 2008 ;
Location in patent: Page/Page column 17-18 ;
反应条件
anhydrous potassium sulfate; hydrogen; potassium hydroxide; 5 Pd(II)/C(eggshell)
T=1 - 8°C; 27 h; Autoclave;
参考文献
DAIKIN INDUSTRIES, LTD.; NOSE, Masatoshi; SUZUKI, Atsushi; SUGIYAMA, Akinari
Patent: WO2010/13576 A1, 2010 ;
Location in patent: Page/Page column 8-9 ;
反应条件
hydrogen; 0.5percent Pd/Al2O3 fluorinated by HF
T=200°C; Product distribution / selectivity;
参考文献
E. I. DU PONT DE NEMOURS AND COMPANY
Patent: WO2008/79265 A1, 2008 ;
Location in patent: Page/Page column 17-18 ;
