1: isopropenylbenzene With PyBH2I in dichloromethane T=20°C; 2 h; 2: With sodium hydroxide; water in dichloromethane T=0 - 20°C; 3: 2,3-dimethylbutane-2,3-diol in dichloromethane; water T=20°C; 15 h;
参考文献
Karatjas, Andrew G.; Vedejs, Edwin
Journal of Organic Chemistry, 2008 , vol. 73, # 23 p. 9508 - 9510
1: With potassium carbonate in methanol; toluene T=60°C; Michael type reaction; 96 h; Inert atmosphere; 2: With water; ammonium chloride in methanol; toluene Inert atmosphere;
参考文献
Cano, Rafael; Ramon, Diego J.; Yus, Miguel
Journal of Organic Chemistry, 2010 , vol. 75, # 10 p. 3458 - 3460
[rhodium(I)chloride(triphenylphosphine)2]1 in toluene; acetonitrile in nitrogen-filled glove box soln. of (BO2C2(CH3)4)2 and α-Me styrene in toluene/acetonitrile added to soln. of trans-Rh(Cl)(CO)(PPh3)2 (catalyst) in same solvent; mixt. stirred, transferred in sealed ampoule and heated to 80°C; not isolated, detn. by GC-MS and NMR;
参考文献
Coapes, R. Benjamin; Souza, Fabio E. S.; Thomas, Rhodri Ll.; Hall, Jonathan J.; Marder, Todd B.
Chemical Communications, 2003 , # 5 p. 614 - 615
[rhodium(I)chloride(triphenylphosphine)2]1 in acetonitrile-D3; benzene-d6 T=80°C; 48 h;
参考文献
Mkhalid, Ibraheem A. I.; Coapes, R. Benjamin; Edes, S. Natasha; Coventry, David N.; Souza, Fabio E. S.; Thomas, Rhodri Ll.; Hall, Jonathan J.; Bi, Si-Wei; Lin, Zhenyang; Marder, Todd B.
Dalton Transactions, 2008 , # 8 p. 1055 - 1064
palladium on activated charcoal in further solvent(s) byproducts: H2; 16 h at 100°C in isopropylbenzene under N2; catalyst: 10percent Pd/C (6molpercent);
