ethene in neat (no solvent)
decompn. on storing at 20°C in presence of ethene (several h, Ar);; condensation into a cooled trap (-78°C, E-4 Torr); contaminated;;
参考文献
Poerschke, Klaus-Richard; Wilke, Guenther; Mynott, Richard
Chemische Berichte, 1985 , vol. 118, # 1 p. 298 - 312
in not given
byproducts: 1,2-bis(2-methylphenyl)ethane; N2 atmosphere; the pyridine complex was treated with an excess of PMe3 at -60°C;; not isolated, detected by NMR spectroscopy;;
参考文献
Carmona, Ernesto; Marin, Jose M.; Paneque, Margarita; Poveda, Manuel L.
Organometallics, 1987 , vol. 6, p. 1757 - 1765
in tetrahydrofuran
stirring ((C5H5)2Zr(CH2PMe2)2)2Ni (1.5 mmol) with ((CH3)3PH)Cl (6.0 mmol) for 2 h in THF at room temp.;; removal of solvent in vac.; sepn by extg. residue with pentane;;
参考文献
Karsch, Hans H.; Mueller, Gerhard; Krueger, Carl
Journal of Organometallic Chemistry, 1984 , vol. 273, # 2 p. 195 - 212
in tetrahydrofuran
stirring ((C5H5)2Zr(CH2PMe2)2 (2.69 mmol) with ((CH3)3P)2NiCl2 (2.70 mmol) for 6 h in THF at 0°C;; removal of solvent in vac.; sepn by extg. residue with pentane;;
参考文献
Karsch, Hans H.; Mueller, Gerhard; Krueger, Carl
Journal of Organometallic Chemistry, 1984 , vol. 273, # 2 p. 195 - 212
in diethyl ether
(under oxygen-free nitrogen) addn. of PMe3 fo Ni-complex in Et2O, stirring (room temp., 3 h), pptn. on cooling (-30°C); filtration, evapn. to dryness;
参考文献
Carmona, Ernesto; Paneque, Margarita; Poveda, Manuel L.
Polyhedron, 1989 , vol. 8, p. 285 - 292
→
反应条件
in diethyl ether
参考文献
Klein, H.-F.; Karsch, H. H.
Chemische Berichte, 1973 , vol. 106, p. 1433 - 1452
Full Text Show Details
Gmelin Handbook: Ni: Org.Verb.1, 1.1.1.2.1.1, page 67 - 79
