(Z)-8-十二烯基乙酸酯合成路线 （共 53 条）
参考文献
Aukrust, Audun; Rongved, Pal; Skatteboel, Lars
Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1985 , vol. 39, # 4 p. 267 - 272
反应条件
1: NaH / dimethylsulfoxide 2: LiAlH4 / diethyl ether 3: H2 / Lindlar catalyst / methanol 4: Py / benzene View Scheme
参考文献
Kovaleva,A.S. et al.
Journal of Organic Chemistry USSR (English Translation), 1972 , vol. 8, p. 2523 - 2527
Zhurnal Organicheskoi Khimii, 1972 , vol. 8, p. 2474 - 2479
反应条件
1: NaH / dimethylsulfoxide 2: LiAlH4 / diethyl ether 3: H2 / Lindlar catalyst / methanol 4: Py / benzene View Scheme
参考文献
Kovaleva,A.S. et al.
Journal of Organic Chemistry USSR (English Translation), 1972 , vol. 8, p. 2523 - 2527
Zhurnal Organicheskoi Khimii, 1972 , vol. 8, p. 2474 - 2479
反应条件
1: LiAlH4 / diethyl ether 2: H2 / Lindlar catalyst / methanol 3: Py / benzene View Scheme
参考文献
Kovaleva,A.S. et al.
Journal of Organic Chemistry USSR (English Translation), 1972 , vol. 8, p. 2523 - 2527
Zhurnal Organicheskoi Khimii, 1972 , vol. 8, p. 2474 - 2479
反应条件
1: 89 percent / NH2 / tetrahydrofuran; dimethylsulfoxide 2: 1) 9-BBN, 2) H2O2, AcONa 3: 85 percent / H2 / Ni-P2 4: 89 percent / pyridine View Scheme
参考文献
Ishmuratov; Ishmuratova; Odinokov; Tolstikov
Chemistry of Natural Compounds, 1997 , vol. 33, # 1 p. 25 - 30
反应条件
1: n-PrLi / diethyl ether; tetrahydrofuran; benzene / -20 -> 20 deg C, 1.5 h 2: 1.) HMPA, 2.) KI / 1.) ether, THF, benzene, 20 deg C, 12 h, 2.) glacial acetic acid, reflux, 20 h 3: 7 g / hydrogen / Lindlar catalyst / hexane / 15 °C View Scheme
参考文献
Zakharkin, L. I.; Zhigareva, G. G.; Petrushkina, E. A.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1981 , vol. 30, # 9 p. 1750 - 1752
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1981 , vol. 30, # 9 p. 2131 - 2132
反应条件
1: 1.) HMPA, 2.) KI / 1.) ether, THF, benzene, 20 deg C, 12 h, 2.) glacial acetic acid, reflux, 20 h 2: 7 g / hydrogen / Lindlar catalyst / hexane / 15 °C View Scheme
参考文献
Zakharkin, L. I.; Zhigareva, G. G.; Petrushkina, E. A.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1981 , vol. 30, # 9 p. 1750 - 1752
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1981 , vol. 30, # 9 p. 2131 - 2132
反应条件
1: 90.8 percent / conc.H2SO4 / 4 h / Heating 2: 80.7 percent Turnov. / Ba(OH)2*8H2O / methanol; benzene / 20 h / Ambient temperature 3: 45 percent / lead tetraacetate, pyridine, Cu(OAc)2 / benzene / 3 h / Heating 4: 1) Br2, 2) aq.KOH / 1) CCl4, r.t., 2) 135-145 deg C, 4 h 5: 86.2 percent / conc.H2SO4 / 4 h / Heating 6: 96 percent / LAH / diethyl ether / 2 h / Ambient temperature 7: 90.6 percent / PPTS / CH2Cl2 / 4 h / Ambient temperature 8: 1) n-BuLi, 2) HMPT / 1) THF, hexane, 10 deg C, 2) <25 deg C, 0.5 h 9: 83 percent / AcOH 10: 97 percent / H2, quinoline / 5percent Pd/BaSO4 / methanol View Scheme
参考文献
Ranganathan, S.; Maniktala, Vibha; Kumar, Raaj; Singh, G. P.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1984 , vol. 23, # 12 p. 1197 - 1207
反应条件
1: 1) n-BuLi, 2) HMPT / 1) THF, hexane, 10 deg C, 2) <25 deg C, 0.5 h 2: 83 percent / AcOH 3: 97 percent / H2, quinoline / 5percent Pd/BaSO4 / methanol View Scheme
参考文献
Ranganathan, S.; Maniktala, Vibha; Kumar, Raaj; Singh, G. P.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1984 , vol. 23, # 12 p. 1197 - 1207
反应条件
1: 45 percent / lead tetraacetate, pyridine, Cu(OAc)2 / benzene / 3 h / Heating 2: 1) Br2, 2) aq.KOH / 1) CCl4, r.t., 2) 135-145 deg C, 4 h 3: 86.2 percent / conc.H2SO4 / 4 h / Heating 4: 96 percent / LAH / diethyl ether / 2 h / Ambient temperature 5: 90.6 percent / PPTS / CH2Cl2 / 4 h / Ambient temperature 6: 1) n-BuLi, 2) HMPT / 1) THF, hexane, 10 deg C, 2) <25 deg C, 0.5 h 7: 83 percent / AcOH 8: 97 percent / H2, quinoline / 5percent Pd/BaSO4 / methanol View Scheme
参考文献
Ranganathan, S.; Maniktala, Vibha; Kumar, Raaj; Singh, G. P.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1984 , vol. 23, # 12 p. 1197 - 1207
