1-甲基-2-亚甲基环己烷合成路线 （共 38 条）
反应条件
hydrogen; cationic chelate biphosphine rhodium in methanol T=20°C; P=760 Torr;
参考文献
Brown, John M.; Hall, Stephen A.
Tetrahedron Letters, 1984 , vol. 25, # 13 p. 1393 - 1396
反应条件
hydrogen; cationic chelate biphosphine rhodium in dichloromethane T=20°C; P=760 Torr;
参考文献
Brown, John M.; Hall, Stephen A.
Tetrahedron Letters, 1984 , vol. 25, # 13 p. 1393 - 1396
反应条件
1: Methyltriphenylphosphonium bromide With sodium hydride in dimethyl sulfoxide
T=20°C; 0.75 h; Inert atmosphere;
2: 2-methyl-cyclohexanone in dimethyl sulfoxide
T=20°C; 16 h;
参考文献
Wang, Zhen J.; Jackson, W. Roy; Robinson, Andrea J.
Organic Letters, 2013 , vol. 15, # 12 p. 3006 - 3009
反应条件
9,9-bis(2,3,5,6-tetraphenylphenoxy)-9-titanaoctahydrofluorene
T=100°C;
参考文献
Waratuke, Steven A.; Johnson, Eric S.; Thorn, Matthew G.; Fanwick, Phillip E.; Rothwell, Ian P.
Chemical Communications, 1996 , # 23 p. 2617 - 2618
反应条件
(NBu4)4W10O32 in acetonitrile
T=25°C; Irradiationalso in presence of var. acids; Product distributionQuantum yield;
参考文献
Renneke, Roman F.; Kadkhodayan, Miryam; Pasquali, Marzia; Hill, Craig L.
Journal of the American Chemical Society, 1991 , vol. 113, # 22 p. 8357 - 8367
反应条件
in benzene-d6
react. W-complex with 7-octen-2-one;
参考文献
Bryan, Jeffrey C.; Arterburn, Jeffrey B.; Cook, Gerald K.; Mayer, James M.
Organometallics, 1992 , vol. 11, p. 3965 - 3970
反应条件
thiophenol in tetrahydrofuran
T=-75°C; 0.0166667 h; Irradiation; Title compound not separated from byproducts;
参考文献
Kantorowski, Eric J.; Eisenberg, Shawn W. E.; Fink, William H.; Kurth, Mark J.
Journal of Organic Chemistry, 1999 , vol. 64, # 2 p. 570 - 580
反应条件
1: 90 percent / copper(I) chloride / diethyl ether / 16 h
2: 1) butyl-lithium / 1) THF, hexane, room temp., 40 min; 2) room temp., 2 h
3: 40 percent / BF3*OEt2 / CHCl3; CCl4 / 0.5 h
View Scheme
参考文献
Fleming, Ian; Patel, Shailesh K.; Urch, Christopher J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1989 , p. 115 - 124
反应条件
1: 70 percent / m-chloroperbenzoic acid / CH2Cl2 / 6 h / 0 °C
2: 90 percent / copper(I) chloride / diethyl ether / 16 h
3: 1) butyl-lithium / 1) THF, hexane, room temp., 40 min; 2) room temp., 2 h
4: 40 percent / BF3*OEt2 / CHCl3; CCl4 / 0.5 h
View Scheme
参考文献
Fleming, Ian; Patel, Shailesh K.; Urch, Christopher J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1989 , p. 115 - 124
反应条件
1: 1) butyl-lithium / 1) THF, hexane, room temp., 40 min; 2) room temp., 2 h
2: 40 percent / BF3*OEt2 / CHCl3; CCl4 / 0.5 h
View Scheme
参考文献
Fleming, Ian; Patel, Shailesh K.; Urch, Christopher J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1989 , p. 115 - 124
