in benzene-d6
T=0°C; Irradiationcompeting reaction with corresponding methyl xanthate; showing highest radiophilicity in comparison of reactivity towards isopropyl radical with thionothiocarbonates; variation of molar ratio of reactants; Product distributionMechanism;
参考文献
Barton, Derek H. R.; Chen, Mi ("Jenny"); Jaszberenyi, Joseph Cs.; Rattigan, Bernard; Tang, Dagang
Tetrahedron Letters, 1994 , vol. 35, # 35 p. 6457 - 6460
in benzene-d6
T=0°C; Irradiationother Barton-ester; also competing reaction with corresponding methyl xanthate; further thionothiocarbonates and thionoselenocarbonate; variation of molar ratio of reactants; Product distributionMechanism;
参考文献
Barton, Derek H. R.; Chen, Mi ("Jenny"); Jaszberenyi, Joseph Cs.; Rattigan, Bernard; Tang, Dagang
Tetrahedron Letters, 1994 , vol. 35, # 35 p. 6457 - 6460