2-(1-金刚烷)环氧乙烷合成路线 （共 7 条）
反应条件
sodium carbonate; 3-chloro-benzenecarboperoxoic acid in dichloromethane
参考文献
Daicel Chemical Industries, Ltd.
Patent: US6429314 B1, 2002 ;
反应条件
potassium tert-butylate in dimethyl sulfoxide T=20°C; 20 h;
参考文献
Fokin, Andrey A.; Butova, Ekaterina D.; Barabash, Anastasiya V.; Huu, Nhan N.; Tkachenko, Boryslav A.; Fokina, Natalie A.; Schreiner, Peter R.
Synthetic Communications, 2013 , vol. 43, # 13 p. 1772 - 1777
反应条件
sodium hydroxide in isopropyl alcohol T=35 - 40°C; 1 h; Yield given;
参考文献
Shiryaev, A. K.; Moiseev, I. K.; Boreko, E. I.; Korobchenko, L. V.; Vladyko, G. V.
Pharmaceutical Chemistry Journal, 1990 , vol. 24, # 5 p. 339 - 343
Khimiko-Farmatsevticheskii Zhurnal, 1990 , vol. 24, # 5 p. 23 - 25
反应条件
1: 87 percent / NaBH4, 0.5percent NaOH / propan-2-ol / 1.) from 20 deg C to 25 deg C, 3 h, 2.) from 60 deg C to 70 deg C, 30 min 2: aq. NaOH / propan-2-ol / 1 h / 35 - 40 °C View Scheme
参考文献
Shiryaev, A. K.; Moiseev, I. K.; Boreko, E. I.; Korobchenko, L. V.; Vladyko, G. V.
Pharmaceutical Chemistry Journal, 1990 , vol. 24, # 5 p. 339 - 343
Khimiko-Farmatsevticheskii Zhurnal, 1990 , vol. 24, # 5 p. 23 - 25
反应条件
1: sulfuric acid / 10 h / |Reflux 2: lithium aluminium tetrahydride / diethyl ether / 20 h / |Reflux 3: pyridinium chlorochromate 4: potassium tert-butylate / dimethyl sulfoxide / 20 h / 20 °C View Scheme
参考文献
Fokin, Andrey A.; Butova, Ekaterina D.; Barabash, Anastasiya V.; Huu, Nhan N.; Tkachenko, Boryslav A.; Fokina, Natalie A.; Schreiner, Peter R.
Synthetic Communications, 2013 , vol. 43, # 13 p. 1772 - 1777
反应条件
1: pyridinium chlorochromate 2: potassium tert-butylate / dimethyl sulfoxide / 20 h / 20 °C View Scheme
参考文献
Fokin, Andrey A.; Butova, Ekaterina D.; Barabash, Anastasiya V.; Huu, Nhan N.; Tkachenko, Boryslav A.; Fokina, Natalie A.; Schreiner, Peter R.
Synthetic Communications, 2013 , vol. 43, # 13 p. 1772 - 1777
反应条件
1: lithium aluminium tetrahydride / diethyl ether / 20 h / |Reflux 2: pyridinium chlorochromate 3: potassium tert-butylate / dimethyl sulfoxide / 20 h / 20 °C View Scheme
参考文献
Fokin, Andrey A.; Butova, Ekaterina D.; Barabash, Anastasiya V.; Huu, Nhan N.; Tkachenko, Boryslav A.; Fokina, Natalie A.; Schreiner, Peter R.
Synthetic Communications, 2013 , vol. 43, # 13 p. 1772 - 1777
