1,2-双(二氯磷基)-乙烷合成路线 （共 18 条）
反应条件
phosphorus pentachloride in diethyl ether T=-78°C;
参考文献
Tavtorkin, Alexander N.; Toloraya, Sofia A.; Nifant'Ev, Eduard E.; Nifant'Ev, Ilya E.
Tetrahedron Letters, 2011 , vol. 52, # 7 p. 824 - 825
反应条件
iron; phosphorus trichoride T=215°C; 18 h;
参考文献
Cloke, F. Geoffrey N.; Fyne, Peter J.; Gibson, Vernon C.; Green, Malcolm L. H.; Ledoux, Marc J.; et al.
Journal of Organometallic Chemistry, 1984 , vol. 277, # 1 p. 61 - 74
反应条件
in diethyl ether -78 deg C then r.t. finaly reflux 3 h;
参考文献
Hackett, Marifaith; Ibers, James A.; Whitesides, George M.
Journal of the American Chemical Society, 1988 , vol. 110, # 5 p. 1436 - 1448
反应条件
1: cyclopentyl-bromide With magnesium in diethyl ether 2: DPPECl4 Heating; Further stages.;
参考文献
Fischer, Reinald; Langer, Jens; Malassa, Astrid; Walther, Dirk; Goerls, Helmar; Vaughan, Gavin
Chemical Communications, 2006 , # 23 p. 2510 - 2512
反应条件
n-butyllithium; N,N,N',N,-tetramethylethylenediamine T=-115 - -80°C; 2 h;
参考文献
Bowen, Richard J.; Garner, A. Christopher; Berners-Price, Susan J.; Jenkins, Ian D.; Sue, Rodney E.
Journal of Organometallic Chemistry, 1998 , vol. 554, # 2 p. 181 - 184
反应条件
n-butyllithium in diethyl ether; hexane; chloroform; acetone
参考文献
Smithkline Beckman Corporation
Patent: US4716230 A1, 1987 ;
反应条件
n-butyllithium 1.) ether/hexane, -72 deg C, 5 h, 2.) ether/hexane, -72 deg C -> r.t., 30 min; Yield given. Multistep reaction;
参考文献
Bowen, Richard J.; Garner, A. Christopher; Berners-Price, Susan J.; Jenkins, Ian D.; Sue, Rodney E.
Journal of Organometallic Chemistry, 1998 , vol. 554, # 2 p. 181 - 184
反应条件
magnesium in diethyl ether T=20°C; 24 h;
参考文献
Wursche, Roland; Debaerdemaeker, Tony; Klinga, Martti; Rieger, Bernhard
European Journal of Inorganic Chemistry, 2000 , # 9 p. 2063 - 2070
反应条件
hydrogenchloride; n-butyllithium 1) hexane, Et2O, 10 min; 2) hexane, Et2O, 20 deg C, 2 h; Yield given. Multistep reaction;
参考文献
Chatt, Joseph; Hussain, Wasif; Leigh, G. Jeffery; Ali, Hapipah Mohd.; Pickett, Christopher J.; Rankin, Douglas A.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1985 , p. 1131 - 1136
参考文献
Eisch, John J.; Piotrowski, Andrzej M.; Aradi, Allen A.; Krueger, Carl; Romao, Maria J.
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1985 , vol. 40, # 5 p. 624 - 635
